Characterization of chemically active antifouling paints using electrochemical impedance spectrometry and erosion tests

被引：13

作者：

Bressy, Christine ^{[1
]}

Hugues, Christelle ^{[1
]}

Margaillan, Andre ^{[1
]}

机构：

[1] Univ Toulon & Var, Lab Mat Finalites Specif, EA 3834, F-83162 La Valette Du Var, France

来源：

PROGRESS IN ORGANIC COATINGS | 2009年 / 64卷 / 01期

关键词：

Permeability; Water sorption; Erosion rate; EIS; Antifouling coatings; ORGANIC COATINGS; WATER SORPTION; ACRYLIC RESIN; EIS; METHACRYLATE; POLYMERS; PERFORMANCE; DIFFUSION; BINDERS;

D O I：

10.1016/j.porgcoat.2008.07.014

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The water sorption and solubility parameters of chemically active paints were studied by electrochemical impedance spectrometry (EIS) measurements. Erodible acrylic-based coatings containing biocidal tertiary amines were investigated. Results from EIS measurements show that both the water sorption at saturation and the apparent water diffusion coefficient decrease as the alkyl chain length of the biocidal amines increases from 8 to 16 carbon atoms. The increase of the hydrophobic character of the resulting coatings results to a higher resistance to erosion. Erosion tests performed under static and dynamic conditions show that the seawater conditions can markedly affect the performance of chemically active paints. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：89 / 97

页数：9

共 44 条

[21] New methods for the study of organic coatings by EIS - New insights into attached and free films [J].

Kittel, J ;

Celati, N ;

Keddam, M ;

Takenouti, H .

PROGRESS IN ORGANIC COATINGS, 2001, 41 (1-3) :93-98

[22] Thermal transition effects and electrochemical properties in organic coatings: Part 1 - Initial studies on corrosion protective organic coatings [J].

Li, J ;

Jeffcoate, CS ;

Bierwagen, GP ;

Mills, DJ ;

Tallman, DE .

CORROSION, 1998, 54 (10) :763-771

[23] A CAPACITANCE METHOD FOR MONITORING THE RATE OF POLISHING OF SELF-POLISHING POLYMERS IN THE LABORATORY [J].

MALCOLMELAWES, DJ ;

TACEY, E ;

GOLD, V .

POLYMER TESTING, 1990, 9 (02) :91-101

[24] The sorption characteristics of epoxy coatings electrodeposited on steel during exposure to different corrosive agents [J].

MiskovicStankovic, VB ;

Drazic, DM ;

KacarevicPopovic, Z .

CORROSION SCIENCE, 1996, 38 (09) :1513-1523

[25] Controlled radical polymerization of a trialkylsilyl methacrylate by reversible addition-fragmentation chain transfer polymerization [J].

Nguyen, MN ;

Bressy, C ;

Margaillan, A .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (22) :5680-5689

[26] Organotin antifouling paints and their alternatives [J].

Omae, I .

APPLIED ORGANOMETALLIC CHEMISTRY, 2003, 17 (02) :81-105

[27] Soft acrylic resin materials containing a polymerisable plasticiser - II: Water absorption characteristics [J].

Parker, S ;

Martin, D ;

Braden, M .

BIOMATERIALS, 1999, 20 (01) :55-60

[28]

Perera D.Y., 1973, PROG ORG COAT, V2, P57, DOI [10.1016/0300-9440(73)80016-5, DOI 10.1016/0300-9440(73)80016-5]

[29] ANOMALOUS DIFFUSION OF WATER IN GLASSY POLYMERS [J].

POGANY, GA .

POLYMER, 1976, 17 (08) :690-694

[30]

Schult KA, 1997, J POLYM SCI POL PHYS, V35, P993, DOI 10.1002/(SICI)1099-0488(19970430)35:6<993::AID-POLB13>3.0.CO

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