Characterization of chemically active antifouling paints using electrochemical impedance spectrometry and erosion tests

被引:13
作者
Bressy, Christine [1 ]
Hugues, Christelle [1 ]
Margaillan, Andre [1 ]
机构
[1] Univ Toulon & Var, Lab Mat Finalites Specif, EA 3834, F-83162 La Valette Du Var, France
关键词
Permeability; Water sorption; Erosion rate; EIS; Antifouling coatings; ORGANIC COATINGS; WATER SORPTION; ACRYLIC RESIN; EIS; METHACRYLATE; POLYMERS; PERFORMANCE; DIFFUSION; BINDERS;
D O I
10.1016/j.porgcoat.2008.07.014
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The water sorption and solubility parameters of chemically active paints were studied by electrochemical impedance spectrometry (EIS) measurements. Erodible acrylic-based coatings containing biocidal tertiary amines were investigated. Results from EIS measurements show that both the water sorption at saturation and the apparent water diffusion coefficient decrease as the alkyl chain length of the biocidal amines increases from 8 to 16 carbon atoms. The increase of the hydrophobic character of the resulting coatings results to a higher resistance to erosion. Erosion tests performed under static and dynamic conditions show that the seawater conditions can markedly affect the performance of chemically active paints. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:89 / 97
页数:9
相关论文
共 44 条
[11]   TRIORGANOSILYL METHACRYLATES - KINETIC-STUDIES OF RADICAL HOMOPOLYMERIZATION AND RADICAL COPOLYMERIZATION WITH METHYL-METHACRYLATE [J].
DURAND, P ;
MARGAILLAN, A ;
CAMAIL, M ;
VERNET, JL .
POLYMER, 1994, 35 (20) :4392-4396
[12]  
Hartshorn L., 1937, Journal of the Society of Chemical Industry, V56, P266
[13]   Different strategies for marine antifouling paints [J].
Hugues, C ;
Bressy, C ;
Margaillan, A .
ANNALES DE CHIMIE-SCIENCE DES MATERIAUX, 2003, 28 (03) :91-107
[14]   Complexation of an acrylic resin by tertiary amines: synthesis and characterisation of new binders for antifouling paints [J].
Hugues, C ;
Bressy, C ;
Bartolomeo, P ;
Margaillan, A .
EUROPEAN POLYMER JOURNAL, 2003, 39 (02) :319-326
[15]   WATER PERMEATION IN COATINGS [J].
HULDEN, M ;
HANSEN, CM .
PROGRESS IN ORGANIC COATINGS, 1985, 13 (3-4) :171-194
[16]  
HUNTER J, 1993, Patent No. 0529693
[17]  
IWAO SO, 2003, CHEM REV, V103, P3431
[18]  
Kennish M.J., 1989, Practical Handbook of Marine Science
[19]   Seawater-soluble pigments and their potential use in self-polishing antifouling paints: simulation-based screening tool [J].
Kiil, S ;
Dam-Johansen, K ;
Weinell, CE ;
Pedersen, MS .
PROGRESS IN ORGANIC COATINGS, 2002, 45 (04) :423-434
[20]   Dynamic simulations of a self-polishing antifouling paint exposed to seawater [J].
Kiil, S ;
Dam-Johansen, K ;
Weinell, CE ;
Pedersen, MS ;
Codolar, SA .
JOURNAL OF COATINGS TECHNOLOGY, 2002, 74 (929) :45-54