Advances in the asymmetric epoxidation of double bond using salen manganese(III) complexes as catalysts

被引：0

作者：

Wang, XY ^{[1
]}

Shi, HC ^{[1
]}

Xu, SY ^{[1
]}

机构：

[1] Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 21卷 / 12期

关键词：

salen manganese(III) complexes; unfunctionalized olefin; asymmetric epoxidation; enantioselectivity;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric epoxidation of unfunctionalized olefins catalyzed by chiral salen manganese (III) complexes is reviewed. The type of catalysts, the mechanism of epoxidation, as well as the scope of the reaction are discussed.

引用

页码：1102 / 1111

页数：10

共 56 条

[1] Synthesis of optically active α-hydroxy carbonyl compounds by the catalytic, enantioselective oxidation of silyl enol ethers and ketene acetals with (salen)manganese(III) complexes
Adam, W
Fell, RT
Stegmann, VR
Saha-Möller, CR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (04) : 708 - 714
[2] CATIONIC ALUMINUM COMPOUNDS WITH POTENTIAL RELEVANCE TO LEWIS-ACID CATALYSIS
ATWOOD, DA
JEGIER, JA
RUTHERFORD, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (25) : 6779 - 6780
[3] REGIOSELECTIVE AND CHEMOSELECTIVE SYNTHESIS OF HALOHYDRINS BY CLEAVAGE OF OXIRANES WITH METAL-HALIDES
BONINI, C
RIGHI, G
[J]. SYNTHESIS-STUTTGART, 1994, (03): : 225 - 238
[4] HIGHLY ENANTIOSELECTIVE, CATALYTIC EPOXIDATION OF TRISUBSTITUTED OLEFINS
BRANDES, BD
JACOBSEN, EN
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (16): : 4378 - 4380
[5] BRANDES BD, 1995, TETRAHEDRON LETT, V36, P5123
[6] REGIOSELECTIVE AND ENANTIOSELECTIVE CATALYTIC EPOXIDATION OF CONJUGATED POLYENES - FORMAL SYNTHESIS OF LTA(4) METHYL-ESTER
CHANG, S
LEE, NH
JACOBSEN, EN
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (25): : 6939 - 6941
[7] ENANTIOSELECTIVE EPOXIDATION OF CYCLIC 1,3-DIENES CATALYZED BY A STERICALLY AND ELECTRONICALLY OPTIMIZED (SALEN)MN COMPLEX
CHANG, S
HEID, RM
JACOBSEN, EN
[J]. TETRAHEDRON LETTERS, 1994, 35 (05) : 669 - 672
[8] EFFECT OF CHIRAL QUATERNARY AMMONIUM-SALTS ON (SALEN)MN-CATALYZED EPOXIDATION OF CIS-OLEFINS - A HIGHLY ENANTIOSELECTIVE, CATALYTIC ROUTE TO TRANS-EPOXIDES
CHANG, SB
GALVIN, JM
JACOBSEN, EN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (15) : 6937 - 6938
[9] A PRACTICAL, HIGHLY ENANTIOSELECTIVE SYNTHESIS OF THE TAXOL SIDE-CHAIN VIA ASYMMETRIC CATALYSIS
DENG, L
JACOBSEN, EN
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (15): : 4320 - 4323
[10] EWINS RC, 1967, J CHEM SOC CHEM COMM, P1089

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