Compounds with the "maple leaf" lattice:: Synthesis, structure, and magnetism of Mx[Fe(O2CCH2)2NCH2PO3]6•nH2O

被引：47

作者：

Cave, D

Coomer, FC

Molinos, E

Klauss, HH

Wood, PT

机构：

[1] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England

[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Phys Kondensierten Mat, D-3300 Braunschweig, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 05期

关键词：

geometric frustration; hydrothermal synthesis; iron magnetic properties; phosphonates;

D O I：

10.1002/anie.200502847

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Turning over a new leaf: In the title iron phosphonate compounds, triangles and hexagons fuse together to generate a maple leaf lattice (see polyhedral representation; green Fe, purple P). This lattice is a new type of topologically frustrated antiferromagnetic network. Exotic forms of magnetic behavior are often encountered in such frustrated materials. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：803 / 806

页数：4

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