Resolving the characteristics of morphotropic phase boundary in the (1-x)Pb(Fe1/2Nb1/2)O3-xPbTiO3 system: A combined dielectric and synchrotron x-ray diffraction study

被引:25
作者
Singh, Satendra Pal [1 ]
Pandey, Dhananjai [1 ]
Yoon, Songhak [2 ]
Baik, Sunggi [2 ]
Shin, Namsoo [3 ]
机构
[1] Banaras Hindu Univ, Inst Technol, Sch Mat Sci & Technol, Varanasi 221005, Uttar Pradesh, India
[2] Pohang Univ Sci & Technol, Dept Mat Sci & Engn, Pohang 790784, South Korea
[3] Pohang Univ Sci & Technol, Pohang Accelerator Lab, Pohang 790784, South Korea
关键词
dielectric materials; electrodes; grain boundaries; lead compounds; multiferroics; permittivity; solid-state phase transformations; X-ray diffraction;
D O I
10.1063/1.3012378
中图分类号
O59 [应用物理学];
学科分类号
摘要
Frequency dependent dielectric studies on the mixed system (1-x)Pb(Fe1/2Nb1/2)O-3-xPbTiO(3) reveal contributions from the electrodes, grain boundaries, and grains. It is shown that the intrinsic value of the dielectric permittivity coming only from the grains peaks at x=0.08. Analysis of synchrotron x-ray diffraction profiles using the Rietveld technique shows that this peaking is linked with a monoclinic to tetragonal morphotropic phase transition in the multiferroic system.
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页数:3
相关论文
共 20 条
[1]  
BERLINCOURT D, 1960, SC4443RR
[2]   Morphotropic phase boundary in (1-x)BiFeO3-xPbTiO3:: phase coexistence region and unusually large tetragonality [J].
Bhattacharjee, Shuvrajyoti ;
Tripathi, Saurabh ;
Pandey, Dhananjai .
APPLIED PHYSICS LETTERS, 2007, 91 (04)
[3]   Antiferrodistortive phase transition in Pb(Ti0.48Zr0.52)O3:: Space group of the lowest temperature monoclinic phase -: art. no. 212101 [J].
Hatch, DM ;
Stokes, HT ;
Ranjan, R ;
Ragini ;
Mishra, SK ;
Pandey, D ;
Kennedy, BJ .
PHYSICAL REVIEW B, 2002, 65 (21) :2121011-2121013
[4]   Morphotropic phase boundary of heterovalent perovskite solid solutions:: Experimental and theoretical investigation of PbSc1/2Nb1/2O3-PbTiO3 -: art. no. 104106 [J].
Haumont, R ;
Al-Barakaty, A ;
Dkhil, B ;
Kiat, JM ;
Bellaiche, L .
PHYSICAL REVIEW B, 2005, 71 (10)
[5]  
Jaffe B., 1971, PIEZOELECTRIC CERAMI
[6]  
Jonscher A., 1983, DIELECTRIC RELAXATIO
[7]   Rietveld refinements of the paraelectric and ferroelectric structures of PbFe0.5Nb0.5O3 [J].
Lampis, N ;
Sciau, P ;
Lehmann, AG .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1999, 11 (17) :3489-3500
[8]   A monoclinic ferroelectric phase in the Pb(Zr1-xTix)O3 solid solution [J].
Noheda, B ;
Cox, DE ;
Shirane, G ;
Gonzalo, JA ;
Cross, LE ;
Park, SE .
APPLIED PHYSICS LETTERS, 1999, 74 (14) :2059-2061
[9]   Tetragonal-to-monoclinic phase transition in a ferroelectric perovskite:: The structure of PbZr0.52Ti0.48O3 [J].
Noheda, B ;
Gonzalo, JA ;
Cross, LE ;
Guo, R ;
Park, SE ;
Cox, DE ;
Shirane, G .
PHYSICAL REVIEW B, 2000, 61 (13) :8687-8695
[10]   Neutron diffraction study of field-cooling effects on the relaxor ferroelectric Pb[(Zn1/3Nb2/3)0.92Ti0.08]O3 -: art. no. 094111 [J].
Ohwada, K ;
Hirota, K ;
Rehrig, PW ;
Fujii, Y ;
Shirane, G .
PHYSICAL REVIEW B, 2003, 67 (09)