Low-temperature synthesis routes of alkali-metal molybdenum bronzes

被引：6
|
作者：
Eda, K [1 ]
Chin, K
Whittingham, MS
机构：
[1] Kobe Univ, Fac Sci, Dept Chem, Nada Ku, Kobe, Hyogo 6578501, Japan
[2] SUNY Binghamton, Inst Mat Res, Binghamton, NY 13902 USA
来源：
CHEMISTRY LETTERS | 1999年 / 08期
关键词：
D O I：
10.1246/cl.1999.811
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We found some novel synthesis routes for alkali-metal molybdenum bronzes. The synthesis techniques are composed of simple hydrothermal treatments of mixed-valence compounds (or mixtures) with ACl or ACl+AOH aqueous solutions (A=alkali metal). Using these routes blue bronze (K0.30MoO3) and red bronze (K0.33MoO3) were obtained from hydrogen molybdenum bronze HXMoO3 or HXMoO3 + MoO3 even at 410 K.
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收藏
页码：811 / 812
页数：2
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