The Reaction of Tertiary Anilines with Maleimides under Visible Light Redox Catalysis

被引:135
作者
Ju, Xuhui [1 ]
Li, Dianjun [1 ]
Li, Weifei [1 ]
Yu, Wei [1 ]
Bian, Fengling [1 ]
机构
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
关键词
aerobic oxidation; maleimides; photocatalysis; tertiary anilines; tetrahydroquinolines; C-H FUNCTIONALIZATION; ELECTRON-TRANSFER PET; PHOTOREDOX CATALYSIS; SYNTHETIC APPLICATIONS; CYCLIZATION REACTIONS; COUPLING REACTION; MOLECULAR-OXYGEN; BOND FORMATION; AMINES; PHOTOCATALYSIS;
D O I
10.1002/adsc.201200608
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Tertiary anilines can be prompted to react with N-aryl- and N-benzylmaleimides to form tetrahydroquinoline products under photocatalysis using visible light irradiation, the ruthenium or iridium complexes Ru(bpy)3Cl2 or Ir(ppy)2(dtbbpy)PF6 as catalyst, and air as terminal oxidant.
引用
收藏
页码:3561 / 3567
页数:7
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