How double volcanic chains sample geochemical anomalies from the lowermost mantle

The distinct isotopic compositions of basalts from the two parallel tracks of Hawaiian volcanoes suggest a bilateral zonation of the underlying mantle plume, with an enriched southern side. Such zonation is not unique to Hawaii, but may well be a common feature of other Pacific hotspots. This remarkable isotopic pattern, revealed by double volcanic chains, appears to be related to the so-called DUPAL isotopic anomaly in the Pacific mantle, which correlates with the seismically imaged 'Large Low-Shear-Velocity Province'. Here we show how a large-scale isotopic gradient, exemplified by the radiogenic isotope ratio Pb-208*/Pb-206*, VD maps from the deep mantle into the Hawaiian plume conduit, and how it ultimately surfaces as Pb-208*/Pb-206* variations in double-chain volcanoes. Our numerical simulations reveal a novel 'lobate' conduit structure which generates an overall bilateral isotopic zonation within the Hawaiian melting zone. Comparison between our model predictions and Pb-208*/Pb-206* of several Hawaiian volcanoes shows that a deep-seated, north-south, isotopic gradient can explain the enriched southern (Loa) chain as well as the Pb-208*/Pb-206* decline from shield to post-shield lavas, observed in several of the volcanoes. The results provide a mechanism for directly linking geochemical maps of ocean island basalts to the structure and composition of the lowermost mantle inferred by seismic tomography. (C) 2012 Elsevier B.V. All rights reserved.