Dipolar molecules inside C70: an electric field-driven room-temperature single-molecule switch

被引：47

作者：

Foroutan-Nejad, Cina ^{[1
]}

Andrushchenko, Valery ^{[2
]}

Straka, Michal ^{[2
]}

机构：

[1] Masaryk Univ, CEITEC Cent European Inst Technol, Kamenice 5-A4, CZ-62500 Brno, Czech Republic

[2] Czech Acad Sci, Inst Organ Chem & Biochem, Flemingovo Nam 1, Prague 16610, Czech Republic

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2016年 / 18卷 / 48期

关键词：

SELF-ASSEMBLED MONOLAYERS; C-60; COMPLEXES; MECHANISM; METALS;

D O I：

10.1039/c6cp06986j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We propose a two-state electric field-driven room-temperature single-molecule switch based on a dipolar molecule enclosed inside ellipsoidal fullerene C-70. We show that the two low-energy minima of the molecular dipole inside the C-70 cage provide distinguishable molecular states of the system that can be switched by application of an external electric field.

引用

页码：32673 / 32677

页数：5

共 36 条

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[24] TRANSMISSION ELECTRON-MICROSCOPY OF C-70 SINGLE-CRYSTALS AT ROOM-TEMPERATURE
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LIN, XW
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[25] Electric-field sensing with driven-dissipative time crystals in room-temperature Rydberg vapor
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