Dipolar molecules inside C70: an electric field-driven room-temperature single-molecule switch

被引：47

作者：

Foroutan-Nejad, Cina ^{[1
]}

Andrushchenko, Valery ^{[2
]}

Straka, Michal ^{[2
]}

机构：

[1] Masaryk Univ, CEITEC Cent European Inst Technol, Kamenice 5-A4, CZ-62500 Brno, Czech Republic

[2] Czech Acad Sci, Inst Organ Chem & Biochem, Flemingovo Nam 1, Prague 16610, Czech Republic

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2016年 / 18卷 / 48期

关键词：

SELF-ASSEMBLED MONOLAYERS; C-60; COMPLEXES; MECHANISM; METALS;

D O I：

10.1039/c6cp06986j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We propose a two-state electric field-driven room-temperature single-molecule switch based on a dipolar molecule enclosed inside ellipsoidal fullerene C-70. We show that the two low-energy minima of the molecular dipole inside the C-70 cage provide distinguishable molecular states of the system that can be switched by application of an external electric field.

引用

页码：32673 / 32677

页数：5

共 36 条

[1] Designing a robust single-molecule switch A single-molecule switch works at room temperature
Frisbie, C. Daniel
SCIENCE, 2016, 352 (6292) : 1394 - 1395
[2] Electric field-driven folding of single molecules
Yuan, Saisai
Zhou, Yu
Gao, Tengyang
Chen, Lichuan
Xu, Wei
Duan, Ping
Wang, Juejun
Pan, Zhichao
Tang, Chun
Yang, Yang
Huang, Ruiyun
Xiao, Zongyuan
Hong, Wenjing
CHINESE CHEMICAL LETTERS, 2024, 35 (01)
[3] Electric field-driven folding of single molecules
Saisai Yuan
Yu Zhou
Tengyang Gao
Lichuan Chen
Wei Xu
Ping Duan
Juejun Wang
Zhichao Pan
Chun Tang
Yang Yang
Ruiyun Huang
Zongyuan Xiao
Wenjing Hong
Chinese Chemical Letters, 2024, 35 (01) : 525 - 530
[4] Theoretical studies of room-temperature single-molecule experiments.
Cao, JS
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U240 - U240
[5] An electric field induced reversible single-molecule fluorescence switch
Wu, Ruixiang
Chen, Ruiyun
Qin, Chengbing
Gao, Yan
Qiao, Zhixing
Zhang, Guofeng
Xiao, Liantuan
Jia, Suotang
CHEMICAL COMMUNICATIONS, 2015, 51 (34) : 7368 - 7371
[6] Room-temperature single-molecule fluorescence imaging for terrylene in biphenyl single crystals
Pars, M.
Palm, V.
Rahn, M.
Palm, N.
Kikas, J.
JOURNAL OF LUMINESCENCE, 2008, 128 (5-6) : 838 - 841
[7] Discrimination and interpretation of spectral phenomena by room-temperature single-molecule spectroscopy
Blum, C
Stracke, F
Becker, S
Müllen, K
Meixner, AJ
JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (29): : 6983 - 6990
[8] Platinum-nanogaps for single-molecule electronics: room-temperature stability
Prins, Ferry
Shaikh, Ahson J.
van Esch, Jan H.
Eelkema, Rienk
van der Zant, Herre S. J.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (32) : 14297 - 14301
[9] Room-temperature tracking of chiral recognition process at the single-molecule level
Xu, Ruilin
Liu, Juan
Chen, Feng
Liu, Nianhua
Cai, Yingxiang
Liu, Xiaoqing
Song, Xin
Dong, Mingdong
Wang, Li
NANO RESEARCH, 2015, 8 (11) : 3505 - 3511
[10] Room-temperature tracking of chiral recognition process at the single-molecule level
Ruilin Xu
Juan Liu
Feng Chen
Nianhua Liu
Yingxiang Cai
Xiaoqing Liu
Xin Song
Mingdong Dong
Li Wang
Nano Research, 2015, 8 : 3505 - 3511

← 1 2 3 4 →