MORPHOTROPIC PHASE BOUNDARY IN (Na0.5Bi0.5)TiO3-BaTiO3 LEAD FREE SYSTEM: XRD AND RAMAN SPECTROSCOPY STUDIES

被引：2

作者：

Lidjici, Hamza ^{[1
,2
]}

Khemakhem, Hamadi ^{[3
]}

机构：

[1] Univ Laghouat, Lab Etud & Dev Mat Semicond & Dielect, Route Ghardaia BP 37G, Laghouat, Algeria

[2] Univ Valenciennes & Hainaut Cambresis, Lab Mat & Proc, F-59600 Zi Du Champ De Labbesse, Maubeuge, France

[3] Univ Sfax, Fac Sci Sfax, LMMA, BP 1171, Sfax 3000, Tunisia

来源：

CERAMICS-SILIKATY | 2016年 / 60卷 / 03期

关键词：

NBT-BT lead-free piezoelectric; MPB; XRD; Raman spectroscopy; ELECTRICAL-PROPERTIES; HIGH-FREQUENCY;

D O I：

10.13168/cs.2016.0031

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

In this paper, we report a raman spectroscopy and X-ray diffraction investigations on lead-free (1-x)(Na0.3Bi0.5)TiO3-xBaTiO(3) (NBT-BT) solid solution ceramics over a composition range of 0 <= x <= 0.10 at room temperature. The Raman curves were fitted to the individual Raman peaks. The obtained peaks were analyzed by observing the changes in their respective peak positions and intensities with increasing of BaTiO3. In light of the obtained observations, it is suggested that a MPB of rhombohedral and tetragonal phases of the studied system lies at the composition of x = 0.065. Further support for the obtained MPB was drawn from X-ray diffraction measurements.

引用

页码：205 / 209

页数：5

共 50 条

[1] Effect of bismuth excess on ferroelectric and piezoelectric properties of a (Na0.5Bi0.5)TiO3-BaTiO3 composition near the morphotropic phase boundary
Xu, Qing
Huang, Duan-Ping
Chen, Min
Chen, Wen
Liu, Han-Xing
Kim, Bok-Hee
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 471 (1-2) : 310 - 316
[2] Elastic, dielectric and electromechanical properties of (Bi0.5Na0.5) TiO3-BaTiO3 piezoceramics at the morphotropic phase boundary region
Machado, Rodrigo
dos Santos, Valdeci B.
Ochoa, Diego A.
Cerdeiras, Elena
Mestres, Lourdes
Garcia, Jose E.
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 690 : 568 - 574
[3] XRD, Raman and electrical studies on the (1-x)(Na0.5Bi0.5)TiO3-xBaTiO3 lead free ceramics
Lidjici, Hamza
Lagoun, Brahim
Berrahal, Mokhtar
Rguitti, Mohamed
Hentatti, Med Amine
Khemakhem, Hamadi
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 618 : 643 - 648
[4] Evolution of crystalline phases and morphotropic phase boundary of the (Bi,Na)TiO3-(Bi,K)TiO3-BaTiO3 lead-free ceramic system
Barbosa Quiroga, David Antonio
Camilo Albornoz Diaz, Julio Cesar
Venet, Michel
Rodrigues, Ariano De Giovanni
Florencio, Odila
da Silva, Paulo Sergio, Jr.
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 691 : 498 - 503
[5] Ferroelectric and piezoelectric properties of lead-free Bi0.5Na0.5 TiO3-Bi0.5K0.5TiO3-BaTiO3-thin films near the morphotropic phase boundary
Acharya, Susant Kumar
Kim, Tae-Min
Hyung, Jung-Hwan
Ahn, Byung-Guk
Lee, Sang-Kwon
JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 586 : 549 - 554
[6] High stability of properties in morphotropic phase boundary Bi0.5Na0.5TiO3-BaTiO3 piezoceramics
Machado, Rodrigo
Ochoa, Diego A.
dos Santos, Valdeci B.
Cerdeiras, Elena
Mestres, Lourdes
Garcia, Jose E.
MATERIALS LETTERS, 2016, 183 : 73 - 76
[7] Structural, dielectric and impedance characteristics of (Bi0.5Na0.5) TiO3-BaTiO3 electronic system
Hajra, Sugato
Sahoo, Sushrisangita
Das, Rutuparna
Choudhary, R. N. P.
JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 750 : 507 - 514
[8] An Approach to Improve the Piezoelectric Property of (Bi0.5Na0.5)TiO3-(Bi0.5K0.5)TiO3-BaTiO3 Lead-Free Ceramics
Dai, Ye-Jing
Zhang, Xiao-Wen
Chen, Ke-Pi
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2011, 8 (02) : 423 - 429
[9] Compositional range and electrical properties of the morphotropic phase boundary in the Na0.5Bi0.5TiO3-K0.5Bi0.5TiO3 system
Otonicar, M.
Skapin, S. D.
Spreitzer, M.
Suvorov, D.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2010, 30 (04) : 971 - 979
[10] Phase structure dependence of acceptor doping effects in (Bi0.5Na0.5) TiO3-BaTiO3 lead-free ceramics
Qi, He
Zuo, Ruzhong
Zhou, Xuefan
Zhang, Dou
JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 802 : 6 - 12

← 1 2 3 4 5 →