Indium-mediated reaction of 1,3-dichloro- and 1,3-dibromopropenes with carbonyl compounds, generation of novel 3,2-diindiopropene

被引：22

作者：

Araki, S

Hirashita, T

Shimizu, H

Yamamura, H

Kawai, M

Butsugan, Y

机构：

[1] Department of Applied Chemistry, Nagoya Institute of Technology, Nagoya 466, Gokiso-cho, Showa-ku

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 46期

关键词：

D O I：

10.1016/0040-4039(96)01925-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Indium-mediated reaction of 1,3-dichloropropene with aldehyde gave syn-chlorohydrin predominantly. A similar reaction of 1,3-dibromopropene gave vinyloxirane and homoallyl alcohol; the former is formed from gamma-bromoallylindium via the corresponding bromohydrin, and the latter is considered to be derived from a unique allylic diindium reagent, 3,3-diindiopropene. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：8417 / 8420

页数：4

共 6 条

[1] Regio- and stereoselective allylindation of allenols regulated by a hydroxyl-chelated bicyclic transition state [J].