Synthesis, optical and electrochemical properties of a series of push-pull dyes based on the 2-(3-cyano-4,5,5-trimethylfuran-2(5H)-ylidene) malononitrile (TCF) acceptor

被引：25
作者：
Noirbent, Guillaume [1 ]
Pigot, Corentin [1 ]
Thanh-Tuan Bui [2 ]
Peralta, Sebastien [2 ]
Nechab, Malek [1 ]
Gigmes, Didier [1 ]
Dumur, Frederic [1 ]
机构：
[1] Aix Marseille Univ, ICR UMR7273, CNRS, F-13397 Marseille, France
[2] CY Cergy Paris Univ, LPPI, F-95000 Cergy, France
来源：
DYES AND PIGMENTS | 2021年 / 184卷
关键词：
Push-pull dyes; Solvatochromism; Claisen-schmidt condensation; Visible absorption; Near infrared absorption; TCF; SENSITIZED SOLAR-CELLS; POLYMERIZATION REACTIONS; ELECTRON-ACCEPTOR; PANCHROMATIC DYES; ACID-DERIVATIVES; POLYMETHINE DYES; SMALL-MOLECULE; ORGANIC-DYES; CHROMOPHORES; DESIGN;
D O I：
10.1016/j.dyepig.2020.108807
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A series of chromophores was designed and synthesized using 2-(3-cyano-4,5,5-trimethylfuran-2 (5H) -ylidene) malononitrile (TCF) as the electron acceptor and differing from each other by the use of thirteen different electron donors. The different dyes were characterized for their optical and electrochemical properties and theoretical calculations were also carried out to support the experimental results. By changing the electron donor in the thirteen dyes, chromophores absorbing between 430 nm and 700 nm could be synthesized. Solvatochromism of the different dyes was analyzed in 23 solvents of different polarity and a positive solvatochromism was determined for all chromophores using the semi-empirical solvent polarity scales based on the Kamlet-Taft parameters (pi*) or the Catalan parameters (SdP and SPP).
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页数：12
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