Palladium-Catalyzed Diarylmethyl C(sp3)-C(sp2) Bond Formation: A New Coupling Approach toward Triarylmethanes

被引：87

作者：

Xia, Ying ^{[1
,2
]}

Hu, Fangdong ^{[3
]}

Liu, Zhenxing ^{[1
,2
]}

Qu, Peiyuan ^{[1
,2
]}

Ge, Rui ^{[1
,2
]}

Ma, Chen ^{[3
]}

Zhang, Yan ^{[1
,2
]}

Wang, Jianbo ^{[1
,2
]}

机构：

[1] Peking Univ, BNLMS, Minist Educ, Coll Chem, Beijing 100871, Peoples R China

[2] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China

[3] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 07期

关键词：

ARYL HALIDES; MIGRATORY INSERTION; N-TOSYLHYDRAZONES; SUBSTITUTED OLEFINS; NOBEL LECTURE; ARYLATION; DERIVATIVES; REACTIVITY; COMPLEXES; CARBENE;

D O I：

10.1021/ol400690t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed reductive coupling reactions between N-tosylhydrazones and aryl halides lead to the formation of C(sp(3))-C(sp(2)) bonds. This approach provides a general route for the synthesis of triarylmethanes.

引用

页码：1784 / 1787

页数：4

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