Yttrium doping of Ba0.5Sr0.5Co0.8Fe0.2O3-δ part II: Influence on oxygen transport and phase stability

被引：20

作者：

Unger, Lana-Simone ^{[1
]}

Ruhl, Rian ^{[2
]}

Meffert, Matthias ^{[3
]}

Niedrig, Christian ^{[1
]}

Menesklou, Wolfgang ^{[1
]}

Wagner, Stefan F. ^{[1
]}

Gerthsen, Dagmar ^{[3
]}

Bouwmeester, Henny J. M. ^{[2
]}

Ivers-Tiffee, Ellen ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, Inst Appl Mat Elect & Elect Engn IAM WET, Adenauerring 20 B, D-76131 Karlsruhe, Germany

[2] Univ Twente, MESA Inst Nanotechnol, Fac Sci & Technol, Electrochem Res Grp,Membrane Sci & Technol, Enschede, Netherlands

[3] Karlsruhe Inst Technol, LEM, D-76131 Karlsruhe, Germany

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2018年 / 38卷 / 05期

关键词：

BSCF; Structural stability; Yttrium doping; Oxygen transport membrane; Electrical conductivity relaxation; GRAIN-SIZE; PEROVSKITE; PERMEATION; BSCF; PERMEABILITY; MEMBRANES; (BA0.5SR0.5)(CO0.8FE0.2)O3-DELTA; MICROSTRUCTURE; PERFORMANCE;

D O I：

10.1016/j.jeurceramsoc.2017.12.042

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) in its cubic perovskite phase has attracted much interest for potential use as oxygen transport membrane (OTM) due to its very high oxygen permeability at high temperatures. However, performance degradation due to a sluggish phase decomposition occurs when BSCF is operated below 840 degrees C. Partial B-site substitution of the transition metal cations in BSCF by larger and redox-stable cations has emerged as a potential strategy to improve the structural stability of cubic BSCF. In this study, the influence of yttrium doping (0...10 mol-%) on oxygen transport properties and stability of the cubic BSCF phase is assessed by in situ electrical conductivity relaxation (ECR) and electrical conductivity measurements during long-term thermal annealing both at 700 degrees C and 800 degrees C. Detailed phase analysis is performed by scanning electron microscopy (SEM) after long-term annealing of the samples in air at different temperatures.

引用

页码：2388 / 2395

页数：8

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