A mild access to silver acetylides from trimethylsilyl acetylenes

被引：42
|
作者：
Vitérisi, A [1 ]
Orsini, A [1 ]
Weibel, JM [1 ]
Pale, P [1 ]
机构：
[1] Univ Strasbourg, Lab Synthese & Reactivite Organ, Inst Le Bel, F-67000 Strasbourg, France
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 16期
关键词：
D O I：
10.1016/j.tetlet.2006.02.067
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
1-Triniethylsilyl-1-alkynes are selectively converted to the corresponding silver acetylides. Silver nitrate or triflate a re used under neutral conditions, allowing other functional groups to remain unaffected. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2779 / 2781
页数：3
相关论文
共 50 条
  • [1] A chemoselective deprotection of trimethylsilyl acetylenes catalyzed by silver salts
    Orsini, A
    Vitérisi, A
    Bodlenner, A
    Weibel, JM
    Pale, P
    TETRAHEDRON LETTERS, 2005, 46 (13) : 2259 - 2262
  • [2] Copper(I)-catalyzed cycloaddition of silver acetylides and azides: Incorporation of volatile acetylenes into the triazole core
    Silvestri, Ilaria Proietti
    Andemarian, Fikre
    Khairallah, George N.
    Yap, Su Wan
    Quach, Tim
    Tsegay, Sammi
    Williams, Craig M.
    O'Hair, Richard A. J.
    Donnelly, Paul S.
    Williams, Spencer J.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2011, 9 (17) : 6082 - 6088
  • [3] REACTION OF COPPER ACETYLIDES WITH HALOGENO-ACETYLENES
    CURTIS, RF
    TAYLOR, JA
    TETRAHEDRON LETTERS, 1968, (25) : 2919 - &
  • [4] SYNTHESIS OF ARYL AND HETEROCYCLIC ACETYLENES VIA COPPER ACETYLIDES
    ATKINSON, RE
    CURTIS, RF
    JONES, DM
    TAYLOR, JA
    JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1969, (16): : 2173 - +
  • [5] SYNTHESIS OF ARYL AND HETEROCYCLIC ACETYLENES VIA COPPER ACETYLIDES
    ATKINSON, RE
    CURTIS, RF
    JONES, DM
    TAYLOR, JA
    CHEMICAL COMMUNICATIONS, 1967, (14) : 718 - &
  • [6] REACTION OF COPPER(I) ACETYLIDES WITH HALOGENO-ACETYLENES
    CURTIS, RF
    TAYLOR, JA
    JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1971, (01): : 186 - &
  • [7] BIS(TRIPHENYLPHOSPHINE)PLATINUM ACETYLIDES FROM FUNCTIONALLY SUBSTITUTED ACETYLENES - NEW SYNTHESIS METHOD
    RUSSO, MV
    FURLANI, A
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 165 (01) : 101 - 105
  • [8] SELECTIVE DESILYLATION OF BIS(TRIMETHYLSILYL)ACETYLENES
    HOLMES, AB
    JENNINGSWHITE, CLD
    SCHULTHESS, AH
    AKINDE, B
    WALTON, DRM
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (19) : 840 - 842
  • [9] The organic chemistry of silver acetylides
    Halbes-Letinois, Ulla
    Weibel, Jean-Marc
    Pale, Patrick
    CHEMICAL SOCIETY REVIEWS, 2007, 36 (05) : 759 - 769
  • [10] A new mild procedure for the direct coupling of 1-trimethylsilyl acetylenes with vinyl triflates or aryl iodide
    Halbes, U
    Pale, P
    TETRAHEDRON LETTERS, 2002, 43 (11) : 2039 - 2042
12345