Two- and three-dimensional photoluminescent Cd(II)-carboxylate coordination frameworks bridged by benzenepentacarboxylate and N-donor ligands

被引：5

作者：

Wang, Jing ^{[1
]}

Yang, Su-Hua ^{[1
]}

Zhou, Ai-Ju ^{[1
]}

Liu, Zhao-Qing ^{[1
]}

Zhao, Jie ^{[1
]}

机构：

[1] Guangzhou Univ, Sch Chem & Chem Engn, Guangzhou, Guangdong, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 14期

基金：

美国国家科学基金会;

关键词：

Cd(II); Coordination polymer; Benzenepentacarboxylate; Hydrothermal synthesis; Photoluminescent property; METAL-ORGANIC FRAMEWORKS; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; POLYMERS; LUMINESCENCE; ACID; NETWORK; DESIGN; SERIES;

D O I：

10.1080/00958972.2013.805410

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of Cd(OAc)(2)H2O, benzenepentacarboxylic acid (H(5)bpc), 2,2-bpy/4,4-bpy, and Et3N yield two new coordination polymers [Cd-5(bpc)(2)(2,2-bpy)(4)(H2O)(4)] (1) and [Cd-5(bpc)(2)(4,4-bpy)(2)(H2O)(4)]<bold>3</bold>H2O (2). Complex 1 is a 2-D structure based on six-connected Cd-carboxylate layers. Adjacent layers are linked by - interactions and hydrogen bonds to generate a layered supramolecular network. Complex 2 is a 3-D coordination framework. The bpc ligands adopting (7)-bridging mode connect Cd(II) ions to form a 3-D open framework with elliptic channels, in which the coordinated 4,4-bpy ligands fill to support the whole framework. Complex 2 exhibits strong photoluminescence at room temperature.

引用

页码：2413 / 2422

页数：10

共 41 条

[1]

[Anonymous], 2000, SHELXTL 6 10

[2]

Bu X.-H., 2003, ANGEW CHEM INT EDIT, V40, P3201

[3] Weak Ferromagnetism and Dynamic Magnetic Behavior of Two 2D Compounds with Hydroxy/Carboxylate-Bridged Co(II) Chains [J].

Cheng, Xiao-Ning ;

Xue, Wei ;

Zhang, Wei-Xiong ;

Chen, Xiao-Ming .

CHEMISTRY OF MATERIALS, 2008, 20 (16) :5345-5350

[4] Two new metal-organic frameworks possessing binodal high-connected topologies based on Cd4-clusters and organic ligands [J].

Cui, Ruihai ;

Xu, Guangjuan ;

Jiang, Zhaohua .

JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (02) :222-231

[5] Solvent- and Vapor-Mediated Solid-State Transformations in 1,3,5-Benzenetricarboxylate Metal-Organic Frameworks [J].

Davies, Kate ;

Bourne, Susan A. ;

Oliver, Clive L. .

CRYSTAL GROWTH & DESIGN, 2012, 12 (04) :1999-2003

[6] Highly porous and stable metal-organic frameworks: Structure design and sorption properties [J].

Eddaoudi, M ;

Li, HL ;

Yaghi, OM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (07) :1391-1397

[7] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

[8] Syntheses, crystal structures, and luminescence of two new coordination polymers based on biphenyl-2,2′,4,4′-tetracarboxylate [J].

Gao, Lou-Jun ;

Cao, Pei-Xiang ;

Wang, Ji-Jiang ;

Wu, Ya-Pan ;

Fu, Feng ;

Zhang, Mei-Li ;

Ren, Yi-Xia ;

Hou, Xiang-Yang .

JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (08) :1299-1308

[9] Solvothermal synthesis, structure, and luminescence of a 3-D Cd(II) complex assembled with biphenyl-2,5,2′,5′-tetracarboxylic acid involving in situ ligand reaction [J].

Guo, Shengqi ;

Tian, Dan ;

Luo, Yuhui ;

Zhang, Hong .

JOURNAL OF COORDINATION CHEMISTRY, 2012, 65 (02) :308-315

[10] Unprecedented bilayer topologies in 5- and 6-connected framework polymers [J].

Hill, RJ ;

Long, DL ;

Turvey, MS ;

Blake, AJ ;

Champness, NR ;

Hubberstey, P ;

Wilson, C ;

Schröder, M .

CHEMICAL COMMUNICATIONS, 2004, (16) :1792-1793

← 1 2 3 4 5 →