Kinetics and mechanism of Ru(VIII) catalyzed oxidation of L(-)-sorbose and maltose by sodium metaperiodate in alkaline medium

被引：0

作者：

Gupta, N ^{[1
]}

Rahmani, S ^{[1
]}

Singh, AK ^{[1
]}

机构：

[1] Univ Allahabad, Dept Chem, Allahabad 211002, Uttar Pradesh, India

来源：

OXIDATION COMMUNICATIONS | 1999年 / 22卷 / 02期

关键词：

kinetics and mechanism; sorbose; maltose; alkaline oxidation; sodium metaperiodate; Ru(VIII);

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics and mechanism of Ru(VIII) catalyzed oxidation of L(-) sorbose and maltose by alkaline solution of sodium metaperiodate in the temperature range of 35 - 50 degrees C have been reported. The experimental results show first order kinetics with respect to [NaIO4], [Ru(VIII)] and [OH-] at their lower concentration. The reaction follows identical kinetics, being zero order in each substrate, i.e. L(-) sorbose and maltose. Variation of ionic strength of the medium shows negligible effect. A suitable mechanism in favour of the above observed kinetics has been proposed and various activation parameters have been calculated, which support the proposed mechanism.

引用

页码：237 / 243

页数：7

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