Plasma-assisted oxidation of carbon particle by lattice oxygen on/in oxide catalyst

被引：14

作者：

Sekine, Yasushi ^{[1
]}

Koyama, Hiroshi ^{[1
]}

Matsukata, Masahiko ^{[1
]}

Kikuchi, Eiichi ^{[1
]}

机构：

[1] CREST, Tokyo, Japan

来源：

FUEL | 2013年 / 103卷

关键词：

Lattice oxygen; Carbon particle; Plasma-assisted oxidation; Fluidized bed; DBD plasma; BIOMASS CHAR STRUCTURE; DIESEL EXHAUST-GASES; SOOT OXIDATION; GASIFICATION REACTIVITY; NONTHERMAL PLASMA; COAL CHAR; TEMPERATURE; COMBUSTION; DISCHARGE; BEHAVIOR;

D O I：

10.1016/j.fuel.2011.03.046

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Oxidation of carbon particles by lattice oxygen on/in catalysts was investigated with and without electrical discharge at 673 K in a fluidized bed reactor. Application of dielectric barrier discharge promoted the evolution of lattice oxygen in the oxide catalyst, and oxidation of carbon by the evolved lattice oxygen was accelerated by application of the discharge. The total amount of consumed lattice oxygen in/on the catalyst was not changed by the application of the discharge due to the low diffusion rate of bulk oxygen at low temperature. Metal-loaded catalysts such as Ni/CeO2 evolved larger amounts of lattice oxygen because of interaction between the supported Ni particle and ceria support. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：2 / 6

页数：5

共 30 条

[1] Enhanced soot oxidation by lattice oxygen via La3+-doped CeO2 [J].