Formation of nanoporous nickel oxides for supercapacitors prepared by electrodeposition with hydrogen evolution reaction and electrochemical dealloying

被引:26
|
作者
Jeong, Myung-Gi [1 ]
Zhuo, Kai [1 ]
Cherevko, Serhiy [1 ]
Chung, Chan-Hwa [1 ]
机构
[1] Sungkyunkwan Univ, Sch Chem Engn, Suwon 440746, South Korea
关键词
Nanoporous NiO Foam Electrode; Dendritic Structure; Hydrogen Evolution Reaction; Electrochemical Dealloying; Supercapacitors; COPPER ELECTRODEPOSITS; CODEPOSITION; MORPHOLOGY; CAPACITOR; CO;
D O I
10.1007/s11814-012-0097-x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly nanoporous nickel oxide electrodes were obtained by electrodeposition accompanied by hydrogen evolution reaction and the selective electrochemical dealloying of copper from Ni-(Cu) porous foam. The nanoporous nickel oxide electrodes consequently have numerous dendritic morphologies composed of nanopores with 20-30 nm diameters. The specific capacitances were 428 F g(-1) for as-deposited Ni-(Cu) foam electrode and 1,305 F g(-1) for nanoporous nickel-oxide electrode after dealloying process, respectively. This indicates increased surface area by dealloying process leads to innovative increase of specific capacitance.
引用
收藏
页码:1802 / 1805
页数:4
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