Fabrication of fluorescent nanotubes basel on layer-by-layer assembly via covalent bond

被引:78
作者
Tian, Y [1 ]
He, Q [1 ]
Tao, C [1 ]
Li, JB [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Int Joint Lab, Key Lab Colloid & Interface Sci,Ctr Mol Sci, Beijing 100080, Peoples R China
关键词
D O I
10.1021/la0524768
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A pressure-filter-template approach was employed to prepare fluorescent nanotubes of polyethyleneimine (PEI) and 3,4,9,10-perylenetetracarboxylicdianhydride (PTCDA) through covalent combination in the porous of alumina template based on the layer-by-layer (LbL) assembly technique. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images exhibited a tubular structure of the obtained samples. The wall thickness of the nanotubes is well controlled by varying the assembled cycle number, which is detected by UV-visible spectroscopy. Fourier transform infrared (FT-IR) spectroscopy confirmed the formation of covalent bonds between PEI and PTCDA in nanotubes.
引用
收藏
页码:360 / 362
页数:3
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