Mechanochemical and silica gel-mediated formation of highly electron-poor 1-cyanocarbonylferrocene

被引：13
|
作者：
Nieto, Daniel [1 ]
Bruna, Sonia [1 ]
Merced Montero-Campillo, M. [2 ]
Perles, Josefina [3 ]
Ma Gonzalez-Vadillo, Ana [1 ]
Mendez, Julia [1 ]
Mo, Otilia [2 ]
Cuadrado, Isabel [1 ]
机构：
[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Inorgan, E-28049 Madrid, Spain
[2] Univ Autonoma Madrid, Fac Ciencias, Dept Quim, E-28049 Madrid, Spain
[3] Univ Autonoma Madrid, Fac Ciencias, Serv Interdept Invest, E-28049 Madrid, Spain
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 84期
关键词：
ORGANOMETALLIC MATERIALS; FERROCENE; OXIDATION; ROUTE;
D O I：
10.1039/c3cc44619k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Simple manual grinding of solid cyanomethylferrrocene (1) and silica gel provides a facile one-pot access route to prepare unexpected and highly electron-poor metallocene, 1-cyanocarbonylferrocene (2). Electrochemical measurements supported by computational studies reveal that 2 exhibits the highest Fe-II/Fe-III oxidation potential reported for mono-substituted ferrocenes.
引用
收藏
页码：9785 / 9787
页数：3
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