Tetranuclear Copper(II) Complex with N,N′-bis(2-N-Tosylaminobenzylidene)-1,3-Diaminopropan-2-ol: Crystal structure and magnetic properties

被引：5

作者：

Popov, L. D. ^{[1
]}

Levchenkov, S. I. ^{[2
]}

Shcherbakov, I. N. ^{[1
]}

Suponitskii, K. Yu. ^{[3
]}

Burlov, A. S. ^{[1
]}

Beloborodov, S. S. ^{[1
]}

Lukov, V. V. ^{[1
]}

Kogan, V. A. ^{[1
]}

机构：

[1] Southern Fed Univ, Rostov Na Donu 344104, Russia

[2] Russian Acad Sci, Southern Sci Ctr, Rostov Na Donu, Russia

[3] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 39卷 / 04期

关键词：

CATECHOLASE-LIKE ACTIVITIES; DOUBLE BRIDGED DINUCLEAR; SCHIFF-BASES; EXCHANGE;

D O I：

10.1134/S1070328413040106

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetranuclear copper(II) complex, [Cu4L2(OOCCH2COO)], where L is triply deprotonated bis-N,N'-(2-N-tosylaminobenzylidene)-1,3-diaminopropan-2-ol, in which two binuclear fragments are linked by the malonate dianion, is synthesized. The exchange interaction in the binuclear clusters is shown to be antiferromagnetic (2J = -59 cm(-1)), whereas the intercluster interaction is ferromagnetic (zJ' = 7.5 cm(-1)). The structure of the DMSO solvate of the complex is determined by X-ray diffraction analysis.

引用

页码：342 / 346

页数：5

共 20 条

[1]

[Anonymous], 2005, APEX2 SAINT

[2] Zinc and cadmium complexes with an achiral symmetric helicand.: Crystal structure of an enantiomerically pure Λ-Zn(II) monohelicate [J].