Nonaqueous redox-flow batteries: features, challenges, and prospects

被引:78
作者
Huang, Yan [1 ]
Gu, Shuang [2 ]
Yan, Yushan [2 ]
Li, Sam Fong Yau [1 ]
机构
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
[2] Univ Delaware, Dept Chem & Biomol Engn, Newark, DE 19716 USA
关键词
ANION-EXCHANGE MEMBRANE; ELECTROCHEMICAL PROPERTIES; NAFION MEMBRANE; COMPLEXES; COMPOSITE; CATHODE; POWER;
D O I
10.1016/j.coche.2015.04.001
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
The increasing concern over climate changes and the limited supply of fossil fuels bring into the general realization that we urgently need to maximize the use of renewable energy resources such as solar and wind. Redox-flow batteries are one of the most promising energy storage technologies, overcoming the intermittency of solar and wind energy. In this review, we focus on nonaqueous redox-flow batteries because of their appealing features in comparison with aqueous based systems, including wider voltage windows, intrinsically faster electron-transfer kinetics, and more extended working temperature ranges. The limitations and challenges of nonaqueous redox-flow batteries are also discussed to provide information for the further development of nonaqueous redoxflow batteries.
引用
收藏
页码:105 / 113
页数:9
相关论文
共 47 条
[1]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[2]   Evaluation of electrolytes for redox flow battery applications [J].
Chakrabarti, M. H. ;
Dryfe, R. A. W. ;
Roberts, E. P. L. .
ELECTROCHIMICA ACTA, 2007, 52 (05) :2189-2195
[3]   Coordination stability between metal/ligands interaction by modern spectroscopic studies: IR, electronic, EPR and cyclic voltammetry of cobalt(II) complexes with organic skeleton containing cyclic ligands [J].
Chandra, Sulekh ;
Kumar, Rajiv ;
Singh, Rajeev ;
Jain, Akash Kr. .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2006, 65 (3-4) :852-858
[4]   Chemical redox agents for organometallic chemistry [J].
Connelly, NG ;
Geiger, WE .
CHEMICAL REVIEWS, 1996, 96 (02) :877-910
[5]   Analysis of the electrochemical behaviour of polymer electrolyte fuel cells using simple impedance models [J].
Danzer, Michael A. ;
Hofer, Eberhard P. .
JOURNAL OF POWER SOURCES, 2009, 190 (01) :25-33
[6]   Redox flow cells for energy conversion [J].
de Leon, C. Ponce ;
Frias-Ferrer, A. ;
Gonzalez-Garcia, J. ;
Szanto, D. A. ;
Walsh, F. C. .
JOURNAL OF POWER SOURCES, 2006, 160 (01) :716-732
[7]   Conductivity and viscosity of PC-DEC and PC-EC solutions of LiBOB [J].
Ding, MS ;
Xu, K ;
Jow, TR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (01) :A132-A140
[8]   Semi-Solid Lithium Rechargeable Flow Battery [J].
Duduta, Mihai ;
Ho, Bryan ;
Wood, Vanessa C. ;
Limthongkul, Pimpa ;
Brunini, Victor E. ;
Carter, W. Craig ;
Chiang, Yet-Ming .
ADVANCED ENERGY MATERIALS, 2011, 1 (04) :511-516
[9]   Quaternized poly(phthalazinon ether sulfone ketone) membrane for anion exchange membrane fuel cells [J].
Fang, Jun ;
Shen, Pei Kang .
JOURNAL OF MEMBRANE SCIENCE, 2006, 285 (1-2) :317-322
[10]   Reflections on Future Directions in Organometallic Electrochemistry [J].
Geiger, William E. .
ORGANOMETALLICS, 2011, 30 (01) :28-31