Photooxidation of N,N′-bis(3,5-di-tert.-butylsalicylidene)-1,2-diamino hexane-manganese(III) chloride (Jacobsen catalyst) in chloroform

被引：13
作者：
Kunkely, H [1 ]
Vogler, A [1 ]
机构：
[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 12期
关键词：
photochemistry; salen complexes; manganese complexes;
D O I：
10.1016/S1387-7003(01)00301-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Mn-III(J-salen)Cl (Jacobsen catalyst) with J-salen=N,N'-bis(3,5-di-tert.-butylsaticylidene)-1,2-diaminocyclohexane dianion in CHCl3 is photooxidized by the solvent to a Mn-IV(J-salen) complex, presumably Mn-IV(J-salen)Cl-2, with phi = 0.002 at lambda (irr) = 333 nm. (C) 2001 Elsevier Science BN. All rights reserved.
引用
收藏
页码：692 / 694
页数：3
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