(Pentamethylcyclopentadienyl)ruthenium π-Complexes of Metalloporphyrins: Platforms with Novel Photo- and Electrochemical Properties

被引：17

作者：

Cuesta, Luciano ^{[1
]}

Karnas, Elizabeth ^{[1
]}

Lynch, Vincent M. ^{[1
]}

Sessler, Jonathan L. ^{[1
]}

Kajonkijya, Wiroaj ^{[2
]}

Zhu, Weihua ^{[2
]}

Zhang, Min ^{[2
]}

Ou, Zhongping ^{[2
]}

Kadish, Karl. M. ^{[2
]}

Ohkubo, Kei ^{[3
,4
]}

Fukuzumi, Shunichi ^{[3
,4
]}

机构：

[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA

[2] Univ Houston, Dept Chem, Houston, TX 77204 USA

[3] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan

[4] SORST JST, Suita, Osaka 5650871, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2008年 / 14卷 / 33期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1002/chem.200801748

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hybrid metalloporphyrin-ruthenocene compounds were synthesized to investigate its photo- and electrochemical properties. The study used cyclic voltammetry, UV/Vis spectro-electrochemistry, ESR spectroscopy, and laser flash photolysis analysis to examine the photoinduced electron transfer from the ruthenocene moiety. It was observed during the study that the (pentamethylcyclopentadienyl)ruthenium π-complexes can be used as precursor to prepare multi-metallocene species. The study used elemental analysis, mass spectrometry, NMR, and ESR spectroscopies to investigate the properties of new bimetallic complexes. The study concluded that these ruthenocene metalloporphyrins can be used to develop new photovoltaic devices for various applications.

引用

页码：10206 / 10210

页数：5

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