Atomic Force Microscopy Study of new Sensing Platforms: Cucurbit[n]uril (n=6, 7) on Gold

被引：25

作者：

Blanco, Elias ^{[1
]}

Quintana, Carmen ^{[1
]}

Hernandez, Lucas ^{[1
]}

Hernandez, Pedro ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Analit & Anal Instrumental, E-28049 Madrid, Spain

来源：

ELECTROANALYSIS | 2013年 / 25卷 / 01期

关键词：

Adsorption; Cucurbituril; Gold; Monolayers; ION COMPLEXED CUCURBITURIL; SELF-ASSEMBLED MONOLAYERS; HOST; IMMOBILIZATION; DERIVATIVES; MOLECULES; BEHAVIOR; BINDING; FAMILY; THIN;

D O I：

10.1002/elan.201200379

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

This work presents the comparative study of the spontaneous adsorption of cucurbit[6]uril and cucurbit[7]uril on gold by means of atomic force microscopy. A faster cucurbit[6]uril adsorption was not achieved by the use of a cucurbit[6]uril solution with sodium salts to increment its solubility than by the treatment with a saturated one in water. However, sodium ions promoted the cucurbit[6]uril polymerization on the previously adsorbed layer. The electrode reaction of hydroquinone became irreversible when a cucurbit[6]uril modified gold electrode was used. Cucurbit[7]uril adsorption was faster than for the smaller homologue and multilayers were generated too with high adsorption times.

引用

页码：263 / 268

页数：6

共 27 条

[1] A general and efficient method to form self-assembled cucurbit[n]uril monolayers on gold surfacest [J].

An, Qi ;

Li, Guangtao ;

Tao, Chengan ;

Li, Yan ;

Wu, Yiguang ;

Zhang, Weixia .

CHEMICAL COMMUNICATIONS, 2008, (17) :1989-1991

[2] Cucurbit[n]urils (n=5-8): A Comprehensive Solid State Study [J].

Bardelang, David ;

Udachin, Konstantin A. ;

Leek, Donald M. ;

Margeson, James C. ;

Chan, Gordon ;

Ratcliffe, Christopher I. ;

Ripmeestert, John A. .

CRYSTAL GROWTH & DESIGN, 2011, 11 (12) :5598-5614

[3] A Voltammetric Study of the Interaction Between Cucurbit[6]uril and Divalent Metal Ions [J].

Blanco, Elias ;

Quintana, Carmen ;

Hernandez, Pedro ;

Hernandez, Lucas .

ELECTROANALYSIS, 2010, 22 (17-18) :2123-2130

[4] Alkanethiols Modified Gold Electrodes for Selective Detection of Molecules with Different Polarity and Molecular Size. Application to Vitamin B2 Analysis [J].

Blanco, Elias ;

Dominguez, Carmen S. H. ;

Hernandez, Pedro ;

Vicente Hernandez, Jose ;

Quintana, Carmen ;

Hernandez, Lucas .

ELECTROANALYSIS, 2009, 21 (3-5) :495-500

[5] The use of cucurbit[8]uril host-guest interactions in the development of an electrochemical sensor: characterization and application to tryptophan determination [J].

del Pozo, Maria ;

Hernandez, Pedro ;

Hernandez, Lucas ;

Quintana, Carmen .

JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (35) :13657-13663

[6] Molecular Self-Assembled Monolayers and Multilayers for Organic and Unconventional Inorganic Thin-Film Transistor Applications [J].

DiBenedetto, Sara A. ;

Facchetti, Antonio ;

Ratner, Mark A. ;

Marks, Tobin J. .

ADVANCED MATERIALS, 2009, 21 (14-15) :1407-1433

[7] Covalent deposition of ferritin nanoparticles onto gold surfaces [J].

Dominguez-Vera, Jose M. ;

Welte, Lorena ;

Galvez, Natividad ;

Fernandez, Belen ;

Gomez-Herrero, Julio ;

Zamora, Felix .

NANOTECHNOLOGY, 2008, 19 (02)

[8] Recognition Properties of Cucurbit[7]uril Self-Assembled Monolayers Studied with Force Spectroscopy [J].

Gomez-Casado, Alberto ;

Jonkheijm, Pascal ;

Huskens, Jurriaan .

LANGMUIR, 2011, 27 (18) :11508-11513

[9] DNA binding to mica correlates with cationic radius: Assay by atomic force microscopy [J].

Hansma, HG ;

Laney, DE .

BIOPHYSICAL JOURNAL, 1996, 70 (04) :1933-1939

[10] Columnar one-dimensional coordination polymer formed with a metal ion and a host-guest complex as building blocks: potassium ion complexed cucurbituril [J].

Heo, J ;

Kim, J ;

Whang, D ;

Kim, K .

INORGANICA CHIMICA ACTA, 2000, 297 (1-2) :307-312

← 1 2 3 →