Large photocurrent generation of gold electrodes modified with [60]fullerene-linked oligothiophenes bearing a tripodal rigid anchor

被引:167
作者
Hirayama, D
Takimiya, K
Aso, Y [1 ]
Otsubo, T
Hasobe, T
Yamada, H
Imahori, H
Fukuzumi, S
Sakata, Y
机构
[1] Hiroshima Univ, Dept Appl Chem, Grad Sch Engn, Higashihiroshima 7398527, Japan
[2] Osaka Univ, Dept Mat & Life Sci, Grad Sch Engn, CREST,Japan Sci & Technol Corp, Suita, Osaka 5650871, Japan
[3] Osaka Univ, Inst Sci & Ind Res, Osaka 5670047, Japan
关键词
D O I
10.1021/ja016703d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
[60]Fullerene-linked quarter- and octithiophenes bearing a tripodal rigid anchor have been synthesized as components of highly efficient SAM-based photovoltaic cells. It has been demonstrated that the tripodal anchor plays an important role in preparing a well-organized SAM on a gold electrode, leading to marked enhancement of the photocurrent generation as compared to the reference system with a one-armed anchor. Copyright © 2002 American Chemical Society.
引用
收藏
页码:532 / 533
页数:2
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