Promotion effect of polymer-immobilized neodymium ions on catalytic activity of ultrafine palladium particles

被引：23

作者：

Teranishi, T

Nakata, K

Miyake, M

Toshima, N

机构：

[1] UNIV TOKYO, SCH ENGN, DEPT APPL CHEM, BUNKYO KU, TOKYO 113, JAPAN

[2] JAPAN ADV INST SCI & TECHNOL, SCH MAT SCI, TATSUNOKUCHI, ISHIKAWA 92312, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 04期

关键词：

D O I：

10.1246/cl.1996.277

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Neodymium ions, which are placed close to ultrafine palladium particles by immobilization on water-soluble polymers, did promote the catalytic activity of the palladium particles for hydrogenation of acrylic acid. The acrylic acid is considered to be concentrated around ultrafine palladium particles by coordinating to neodymium ions bound to the protecting polymer.

引用

页码：277 / 278

页数：2

共 9 条

[1]

GSCHNEIDER KA, 1978, HDB PHYSICS CHEM RAR, V1

[2]

GUANGXIAN X, 1985, NEW FRONTIERS RARE E

[3] PHYSICOCHEMICAL PROPERTIES OF SMALL METAL PARTICLES IN SOLUTION - MICROELECTRODE REACTIONS, CHEMISORPTION, COMPOSITE METAL PARTICLES, AND THE ATOM-TO-METAL TRANSITION [J].