Novel triazole-based fluorescent probes for Pd2+ in aqueous solutions: design, theoretical calculations and imaging

被引:34
作者
Hou, Ji-Ting [1 ]
Li, Kun [1 ]
Yu, Kang-Kang [1 ]
Ao, Mei-Zhen [1 ]
Wang, Xin [1 ]
Yu, Xiao-Qi [1 ]
机构
[1] Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Coll Chem, Chengdu 610064, Peoples R China
基金
美国国家科学基金会;
关键词
CLICK CHEMISTRY; PALLADIUM; SENSOR; CHEMOSENSOR; ACID; AG+;
D O I
10.1039/c3an01183f
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The first triazole-containing fluorescent probe with excellent water-solubility for Pd2+ was presented. The results indicated that an amide-triazole-amide binding sequence was responsible for the unique affinity of PS-1 toward Pd2+. Among the tested metal ions, only Pd2+ could selectively quench the fluorescence of PS-1 under physiological conditions, while other common interference ions like Pt2+ and Ru3+ caused little changes. The successful fluorescence imaging of Pd2+ in HeLa cells implied the potential applications of PS-1 in biological Pd2+-analysis.
引用
收藏
页码:6632 / 6638
页数:7
相关论文
共 54 条
[1]  
Ahlquist M.S., 2011, Angew. Chem, V123, P11998, DOI DOI 10.1002/ANGE.201105928
[2]   Cu(I)-Catalyzed Huisgen Azide-Alkyne 1,3-Dipolar Cycloaddition Reaction in Nucleoside, Nucleotide, and Oligonucleotide Chemistry [J].
Amblard, Franck ;
Cho, Jong Hyun ;
Schinazi, Raymond F. .
CHEMICAL REVIEWS, 2009, 109 (09) :4207-4220
[3]   Peptidomimetics via copper-catalyzed azide-alkyne cycloadditions [J].
Angell, Yu L. ;
Burgess, Kevin .
CHEMICAL SOCIETY REVIEWS, 2007, 36 (10) :1674-1689
[4]   Industrial-scale palladium-catalyzed coupling of aryl halides and amines - A personal account [J].
Buchwald, SL ;
Mauger, C ;
Mignani, G ;
Scholz, U .
ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (1-2) :23-39
[5]   Triazole- and azo-coupled calix[4]arene as a highly sensitive chromogenic sensor for Ca2+ and Pb2+ ions [J].
Chang, Kai-Chi ;
Su, In-Hao ;
Lee, Gene-Hsiang ;
Chung, Wen-Sheng .
TETRAHEDRON LETTERS, 2007, 48 (41) :7274-7278
[6]   Triazole-modified calix[4]crown as a novel fluorescent on-off switchable chemosensor [J].
Chang, Kai-Chi ;
Su, In-Hao ;
Senthilvelan, Annamalai ;
Chung, Wen-Sheng .
ORGANIC LETTERS, 2007, 9 (17) :3363-3366
[7]   Palladium(II)-Catalyzed C-H Activation/C-C Cross-Coupling Reactions: Versatility and Practicality [J].
Chen, Xiao ;
Engle, Keary M. ;
Wang, Dong-Hui ;
Yu, Jin-Quan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (28) :5094-5115
[8]   Highly sensitive and selective Pd2+ sensor of naphthalimide derivative based on complexation with alkynes and thio-heterocycle [J].
Duan, Liping ;
Xu, Yufang ;
Qian, Xuhong .
CHEMICAL COMMUNICATIONS, 2008, (47) :6339-6341
[9]   Clicking polymers: a straightforward approach to novel macromolecular architectures [J].
Fournier, David ;
Hoogenboom, Richard ;
Schubert, Ulrich S. .
CHEMICAL SOCIETY REVIEWS, 2007, 36 (08) :1369-1380
[10]  
Frisch M., 2004, GAUSSIAN 03 REVISION, DOI DOI 10.1016/J.MOLSTRUC.2017.03.014