REACTION OF A HETEROTOPIC P,SAs LIGAND WITH GROUP 10 METAL(II) COMPLEXES: A THEORETICAL STUDY

被引：0

作者：

Sarosi, Imola ^{[1
,2
]}

Sarosi, Menyhart B. ^{[1
]}

Hey-Hawkins, Evamarie ^{[2
]}

Silaghi-Dumitrescu, Luminita ^{[1
]}

机构：

[1] Univ Babes Bolyai, Fac Chem & Chem Engn, Cluj Napoca 400028, Romania

[2] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany

来源：

STUDIA UNIVERSITATIS BABES-BOLYAI CHEMIA | 2012年 / 57卷 / 02期

关键词：

heterotopic P; SAs ligand; palladium complexes; platinum complexes; structural isomerism; DFT calculations; EFFECTIVE CORE POTENTIALS; MOLECULAR CALCULATIONS; BOND-CLEAVAGE; PHOSPHORUS; SULFUR; CRYSTAL; MOLYBDENUM;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Density functional calculations have been carried out in order to gain some insight into the electronic structure of 1-Ph2AsSC6H4-2-PPh2 (1) and to investigate the reactions of 1 with group 10 metal dihalides. The obtained results explain well the experimentally observed behaviour of 1 during the investigated complexation reactions and support the trends observed for the isomerisation of the resulted trinuclear trimeric compounds.

引用

页码：139 / 146

页数：8

共 20 条

[1] 2-PHOSPHINOBENZENETHIOLS AND 2-PHOSPHINYLBENZENETHIOLS - NEW LIGAND TYPES
BLOCK, E
OFORIOKAI, G
ZUBIETA, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (06) : 2327 - 2329
[2] Labile SR′C(O)CRCH-bridged dicobalt complexes;: synthesis, structures and 13CO labelling studies
Conole, G
Kessler, M
Mays, MJ
Pateman, GE
Solan, GA
[J]. POLYHEDRON, 1998, 17 (17) : 2993 - 3004
[3] Reactions of thioarsines with metal carbonyls:: synthesis and structural characterisation of [Fe2(CO)6(μ-AsMe2)(μ-SPh)], [Fe2Cp2(CO)2(μ-AsPh2)(μ-SPh)], [Mn2(CO)8(μ-AsPh2)(μ-SPh)] and [Co3(μ3-S)(μ-AsPh2)(CO)6AsPh3]
Conole, G
Davies, JE
King, JD
Mays, MJ
McPartlin, M
Powell, HR
Raithby, PR
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 585 (01) : 141 - 149
[4] The preparation and coordination chemistry of phosphorus-sulfur donor ligands
Dilworth, JR
Wheatley, N
[J]. COORDINATION CHEMISTRY REVIEWS, 2000, 199 : 89 - 158
[5] SELF-CONSISTENT MOLECULAR-ORBITAL METHODS .9. EXTENDED GAUSSIAN-TYPE BASIS FOR MOLECULAR-ORBITAL STUDIES OF ORGANIC MOLECULES
DITCHFIELD, R
HEHRE, WJ
POPLE, JA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1971, 54 (02) : 724 - +
[6] SYNTHESIS AND REACTIONS WITH ALKYNES OF COMPLEXES CONTAINING BOTH PHOSPHORUS AND SULFUR BRIDGING LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURES OF [MN2(LAMBDA-PPH2)-(LAMBDA-SPH)(CO)8], [CO3(LAMBDA-3-S)(LAMBDA-PPH2)(CO)6(PPH3)] AND [CO3(LAMBDA-3-S)(LAMBDA-PPH2CHCPH)(CO)6(PPH3)]
EDWARDS, AJ
MARTIN, A
MAYS, MJ
NAZAR, D
RAITHBY, PR
SOLAN, GA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (03): : 355 - 363
[7] INTERCHANGE OF SPH AND PPH2 GROUPS AT A DICOBALT CENTER - CRYSTAL AND MOLECULAR-STRUCTURES OF [CO2(MU-PPH2)(MU-SPHC(O)CHCH)(CO)4] AND [CO2(MU-SPH)(MU-PPH2CHCHC(O))(CO)2(P(OME)3)2]
EDWARDS, AJ
MARTIN, A
MAYS, MJ
RAITHBY, PR
SOLAN, GA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (19) : 1416 - 1418
[8] Frisch M. J., 2016, Gaussian 03 Revision B.03
[9] WEITERES VERFAHREN ZUR KNUPFUNG VON P - P-BINDUNGEN
FRITZSCHE, H
KORTE, F
HASSERODT, U
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1963, 75 (24) : 1205 - &
[10] Fusco R., 1963, Montecatini, Patent, Patent No. [BE621008, 621008]

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