Syntheses, Structures, and Luminescent Properties of Two Cadmium(II) Coordination Compounds based on a Sulfonate Functionalized Terpyridine Ligand

被引：5

作者：

Shen, Sa-Sa ^{[1
]}

Bai, Chao ^{[1
]}

Hu, Huai-Ming ^{[1
]}

Yuan, Fei ^{[1
]}

Wang, Xiaofang ^{[1
]}

Xue, Ganglin ^{[1
]}

机构：

[1] NW Univ Xian, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian 710127, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2015年 / 641卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Coordination compounds; Cadmium; Helical chain; Interpenetration; Luminescence; BUILDING-BLOCKS; HELICAL CHAINS; POLYMER; CONSTRUCTION; COMPLEXES; ARENEDISULFONATES; DIVERSITY; ACID;

D O I：

10.1002/zaac.201500210

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination compounds [Cd(TBDS)(H2O)(2)](n) (1) and Cd(TBDS)(bpy)(2)(H2O)3H(2)O (2) {H2TBDS = 4-([4,2:6,4-terpyridine]-4-yl)benzene-1,3-disulfonic acid, bpy = 2,2-bipyridine} were synthesized under hydrothermal conditions. Single crystal X-ray diffraction analyses revealed that compound 1 is a twofold interpenetrating 3D framework with 4-connected dia topology, whereas compound 2 is a mononuclear compound, which packed with each other via hydrogen-bonding interactions to construct a three-dimensional supramolecular structure, and contained unusual meso-helical chains. Additionally, the luminescence properties and thermal stabilities of 1 and 2 were investigated.

引用

页码：1772 / 1776

页数：5

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