Eco-friendly synthesis of activated carbon from dead mango leaves for the ultrahigh sensitive detection of toxic heavy metal ions and energy storage applications

被引:166
作者
Madhu, Rajesh [1 ]
Sankar, Kalimuthu Vijaya [2 ]
Chen, Shen-Ming [1 ]
Selvan, Ramakrishnan Kalai [2 ]
机构
[1] Natl Taipei Univ Technol, Dept Chem Engn & Biotechnol, Electroanal & Bioelectrochem Lab, Taipei 106, Taiwan
[2] Bharathiar Univ, Dept Phys, Solid State Ion & Energy Devices Lab, Coimbatore 641046, Tamil Nadu, India
关键词
ANODIC-STRIPPING VOLTAMMETRY; ELECTROCHEMICAL PROPERTIES; SUPERCAPACITOR; MICROWAVE; MORPHOLOGY; LEAD; PRECONCENTRATION; PERFORMANCE; REMOVAL; MERCURY;
D O I
10.1039/c3ra45089a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel spherical carbon nanoparticle decorated activated carbon (SNAC) material with a high surface area of about 1555 m(2) g(-1) is prepared from the dead mango leaves by an eco-friendly method for the detection of toxic heavy metal ions and energy storage applications. The limits of detection (LODs) for the determination of Cd(II), Pb(II), Cu(II), and Hg(II) ions at the SNAC-modified GCE are 24.4 x 10(-9) M, 5.7 x 10(-9) M, 23.2 x 10(-9) M and 24.6 x 10(-9) M, respectively. On the other hand, the obtained maximum specific capacitance for the single electrode from galvanostatic charge discharge is 478 F g(-1) at 1 A g(-1). The symmetric supercapacitor cell provides a higher specific capacitance (SC) of 55 F g(-1) at 1 A g(-1), and energy density of 10.75 W h kg(-1) at a power density of 300 W kg(-1).
引用
收藏
页码:1225 / 1233
页数:9
相关论文
共 54 条
[1]  
Agullo J. A. M., 2007, MICROPOR MESOPOR MAT, V101, P397
[2]   Simultaneous electrochemical determination of arsenic, copper, lead and mercury in unpolluted fresh waters using a vibrating gold microwire electrode [J].
Alves, Georgina M. S. ;
Magalhaes, Julia M. C. S. ;
Salauen, Pascal ;
van den Berg, Constant M. G. ;
Soares, Helena M. V. M. .
ANALYTICA CHIMICA ACTA, 2011, 703 (01) :1-7
[3]   Activated porous carbon nanofibers using Sn segregation for high-performance electrochemical capacitors [J].
An, Geon-Hyoung ;
Ahn, Hyo-Jin .
CARBON, 2013, 65 :87-96
[4]  
[Anonymous], 1999, ELECTROCHEMICAL SUPE
[5]   Solid-phase preconcentration and determination of mercury(II) using activated carbon in drinking water by X-ray fluorescence spectrometry [J].
Aranda, Pedro R. ;
Colombo, Leandro ;
Perino, Ernesto ;
De Vito, Irma E. ;
Raba, Julio .
X-RAY SPECTROMETRY, 2013, 42 (02) :100-104
[6]   INTERMETALLIC COMPOUNDS FORMED IN MIXED (COMPLEX) AMALGAMS .1. SYSTEMS - COPPER-MERCURY, ZINC-MERCURY AND COPPER-ZINC-MERCURY [J].
BENBASSAT, AHI ;
AZRAD, A .
ELECTROCHIMICA ACTA, 1978, 23 (01) :63-69
[7]   From dead leaves to high energy density supercapacitors [J].
Biswal, Mandakini ;
Banerjee, Abhik ;
Deo, Meenal ;
Ogale, Satishchandra .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (04) :1249-1259
[8]   Carbon-based nanostructured materials and their composites as supercapacitor electrodes [J].
Bose, Saswata ;
Kuila, Tapas ;
Mishra, Ananta Kumar ;
Rajasekar, R. ;
Kim, Nam Hoon ;
Lee, Joong Hee .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (03) :767-784
[9]   Artificial neural network processing of stripping analysis responses for identifying and quantifying heavy metals in the presence of intermetallic compound formation [J].
Chan, H ;
Butler, A ;
Falck, DM ;
Freund, MS .
ANALYTICAL CHEMISTRY, 1997, 69 (13) :2373-2378
[10]   Morphology-Dependent Enhancement of the Pseudocapacitance of Template-Guided Tunable Polyaniline Nanostructures [J].
Chen, Wei ;
Rakhi, R. B. ;
Alshareef, H. N. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (29) :15009-15019