Synthesis and properties of C-C conjugated phthalocyanine dimers

被引:9
作者
Ali, Hasrat [1 ]
Baillargeon, Pierre [1 ]
van Lier, Johan E. [1 ]
机构
[1] Univ Sherbrooke, Fac Med & Hlth Sci, Dept Med Nucl & Radiobiol, Sherbrooke, PQ J1H 5N4, Canada
关键词
D O I
10.1016/j.tetlet.2008.09.160
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Covalently C-C linked Pc-Pc homo-dimers (ortho and meta) were synthesized from their corresponding Pc halide precursors using a Pd-catalyzed homo-coupling reaction. Photophysical data reveal energy transfer between the Pc moieties resulting in the appearance of new red-shift Q-bands that correlate to the planarity and dihedral angle between the Subunit. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7253 / 7255
页数:3
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