First example of a rigid (mu-oxo-di-mu-acetato)diiron(III) complex with 1,2-bis[2-di(2-pyridyl)methyl-6-pyridyl]ethane; Its efficient catalysis for functionalization of alkanes

被引：67

作者：

Kodera, M

Shimakoshi, H

Kano, K

机构：

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 15期

关键词：

D O I：

10.1039/cc9960001737

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mu-oxo-di-mu-acetatodiiron(III) complex [Fe-2(hexpy)(O)-(OCOMe)(2)][ClO4](2) (hexpy = 1,2-bis [2-di(2-pyridyl)methyl-6-pyridyl]ethane) efficiently catalyses the oxygenation of cyclohexane, methylcyclohexane and adamantane in the presence of m-chloroperbenzoic acid.

引用

页码：1737 / 1738

页数：2

共 22 条

[1] Synthesis, characterization, and crystal structure of a (mu-oxo)bis(mu-acetato)diiron(III) complex with a dinucleating hexapyridine ligand, 1,2-bis[2-(bis(2-pyridyl)methyl)-6-pyridyl]ethane. The first example of a discrete (mu-oxo)bis(mu-acetato)diiron(III) complex with a dinucleating ligand
Kodera, M
Shimakoshi, H
Nishimura, M
Okawa, H
Iijima, S
Kano, K
INORGANIC CHEMISTRY, 1996, 35 (17) : 4967 - 4973
[2] STRUCTURE OF MU-[1,2-BIS(TERT-BUTYLAMINO-1-2-KAPPA-N)-1,2-DI(2-PYRIDYL-KAPPA-N)ETHANE]-BIS(ETHYLZINC)
SPEK, AL
JASTRZEBSKI, JTBH
VANKOTEN, G
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 2006 - 2007
[3] Synthesis, Characterization, and Crystal Structure of a (ae-Oxo)bis(ae-acetato) diiron(III) Complex with a Dinucleating Hexapyridine Ligand, 1,2-Bis[2-(bis(2-pyridyl)methyl)-6-pyridy l]ethane. The First Example of a Discrete (ae-Oxo)bis(ae-acetato)diiron(III) Complex with a Dinucleating Ligand
Inorg Chem, 17 (4967):
[4] REACTIONS OF 2-PYRIDYLPHENYLACETONITRILE AND 1,2-DICYANO-1,2-DI(PHENYL)-1,2-DI(2-PYRIDYL)ETHANE WITH TITANIUM(IV), VANADIUM(IV), CHROMIUM(III) AND IRON(III) CHLORIDES
MASAGUER, JR
MENDIOLA, MA
TRANSITION METAL CHEMISTRY, 1985, 10 (07) : 243 - 246
[5] SYNTHESIS AND MAGNETIC CHARACTERIZATION OF THE DIOXOHYDROXO-BRIDGED AND OXOHYDROXO-BRIDGED DIMERIC CHROMIUM(III) CATIONS DI-MU-OXOBIS[BIS(1-(2-PYRIDYL)ETHYLAMINE)CHROMIUM(III)] AND MU-OXO-MU-HYDROXOBIS[BIS(1-(2-PYRIDYL)ETHYLAMINE)CHROMIUM(III)], AND STRUCTURE OF THE BROMIDE SALT OF THE OXOHYDROXO COMPLEX
MICHELSEN, K
PEDERSEN, E
WILSON, SR
HODGSON, DJ
INORGANICA CHIMICA ACTA-ARTICLES, 1982, 63 (02): : 141 - 150
[6] DOUBLE-BRIDGED BINUCLEAR CHROMIUM(III) COMPLEX WITH 1-(2-PYRIDYL)ETHYLAMINE - STEREOCHEMICAL AND MAGNETIC-PROPERTIES OF DI-MU-HYDROXOBIS [BIS[1-(2-PYRIDYL)ETHYLAMINE]-CHROMIUM(III)] IONS
MICHELSEN, K
PEDERSEN, E
ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1978, 32 (09): : 847 - 855
[7] 4-COORDINATE, 5-COORDINATE AND 6-COORDINATE METAL COMPLEXES OF DI(2-PYRIDYL) DISULFIDE AND 1,2-DI(2'-PYRIDYL)ETHANE - FURTHER STUDIES OF INFRARED SPECTRA OF PYRIDINE-METAL COMPLEXES
KEETON, M
LEVER, ABP
INORGANIC CHEMISTRY, 1971, 10 (01) : 47 - &
[8] BIS[1,1-DI(2-PYRIDYL)ETHYL METHYL ETHER-N,N',O]COPPER(II) DI-MU-IODO-BIS[IODOARGENTATE(I)]
JONES, PG
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 : 1314 - 1315
[9] DOUBLE-BRIDGED BINUCLEAR CHROMIUM(III) COMPLEX WITH "1,6-BIS(2'-PYRIDYL)-2,5-DIAZAHEXANE - PREPARATION, RESOLUTION AND STEREOCHEMISTRY OF DI-MU-HYDROXOBIS[(1,6-BIS-(2'-PYRIDYL)-2,5-DIAZAHEXANE)CHROMIUM(III)] ION
MICHELSEN, K
ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1977, 31 (06): : 429 - 436
[10] Preparation, structure, and properties of bis(mu-oxo)dirhenium(III,IV) and -dirhenium(IV) - Complexes of tris(2-pyridylmethyl)amine and its (6-methyl-2-pyridyl)methyl derivatives
Sugimoto, H
Kamei, M
Umakoshi, K
Sasaki, Y
Suzuki, M
INORGANIC CHEMISTRY, 1996, 35 (24) : 7082 - 7088

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