First example of a rigid (mu-oxo-di-mu-acetato)diiron(III) complex with 1,2-bis[2-di(2-pyridyl)methyl-6-pyridyl]ethane; Its efficient catalysis for functionalization of alkanes

被引：67

作者：

Kodera, M

Shimakoshi, H

Kano, K

机构：

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 15期

关键词：

D O I：

10.1039/cc9960001737

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mu-oxo-di-mu-acetatodiiron(III) complex [Fe-2(hexpy)(O)-(OCOMe)(2)][ClO4](2) (hexpy = 1,2-bis [2-di(2-pyridyl)methyl-6-pyridyl]ethane) efficiently catalyses the oxygenation of cyclohexane, methylcyclohexane and adamantane in the presence of m-chloroperbenzoic acid.

引用

收藏

页码：1737 / 1738

页数：2

相关论文

共 23 条

[1] A MECHANISTIC PROBE FOR OXYGEN ACTIVATION BY METAL-COMPLEXES AND HYDROPEROXIDES AND ITS APPLICATION TO ALKANE FUNCTIONALIZATION BY [FE(III)CL(2)TRIS(2-PYRIDINYLMETHYL)AMINE](+)BF4- [J].

ARENDS, IWCE ;

INGOLD, KU ;

WAYNER, DDM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (16) :4710-4711

[2]

Dalton H, 1992, BIOTECHNOLOGY HDB, V5, P85

[3] REACTIONS OF NONHEME IRON(II) CENTERS WITH DIOXYGEN IN BIOLOGY AND CHEMISTRY [J].

FEIG, AL ;

LIPPARD, SJ .

CHEMICAL REVIEWS, 1994, 94 (03) :759-805

[4] BIOMIMETIC OXIDATION STUDIES .5. MECHANISTIC ASPECTS OF ALKANE FUNCTIONALIZATION WITH FE,FE2O, AND FE4O2 COMPLEXES IN THE PRESENCE OF HYDROGEN-PEROXIDE [J].

FISH, RH ;

KONINGS, MS ;

OBERHAUSEN, KJ ;

FONG, RH ;

YU, WM ;

CHRISTOU, G ;

VINCENT, JB ;

COGGIN, DK ;

BUCHANAN, RM .

INORGANIC CHEMISTRY, 1991, 30 (15) :3002-3006

[5] ALKANE OXIDATION BY POLYNUCLEAR NONHEME IRON COMPLEXES - AN IMIDAZOLE EFFECT [J].

FONTECAVE, M ;

ROY, B ;

LAMBEAUX, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (14) :939-940

[6] HIGH-VALENT IRON-PORPHYRIN COMPLEXES RELATED TO PEROXIDASE AND CYTOCHROME-P-450 [J].

GROVES, JT ;

HAUSHALTER, RC ;

NAKAMURA, M ;

NEMO, TE ;

EVANS, BJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (10) :2884-2886

[7]

HILL CL, 1989, ACTIVATION FUNCTIONA, P243

[8] HYDROXYLATION OF ALKANES AND ARENES USING MOLECULAR-OXYGEN [J].

KITAJIMA, N ;

ITO, M ;

FUKUI, H ;

MOROOKA, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (02) :102-104

[9] A MODEL FOR METHANE MONO-OXYGENASE - DIOXYGEN OXIDATION OF ALKANES BY USE OF A MU-OXO BINUCLEAR IRON COMPLEX [J].

KITAJIMA, N ;

FUKUI, H ;

MOROOKA, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (07) :485-486

[10]

KODERA M, IN PRESS INORG CHEM