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Conductivities of 1-Alkyl-3-methylimidazolium Chloride Ionic Liquids in Disaccharide plus Water Solutions at 298.15 K
被引:6
|作者:
Chen, Yujuan
[1
]
Fang, Mengyao
[1
]
Bai, Guangyue
[1
]
Zhuo, Kelei
[1
]
Yan, Changling
[1
]
机构:
[1] Henan Normal Univ, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Key Lab Green Chem Media & React, Minist Educ,Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
基金:
中国国家自然科学基金;
关键词:
AQUEOUS-SUCROSE SOLUTIONS;
PHYSICOCHEMICAL PROPERTIES;
VOLUMETRIC PROPERTIES;
MIXED ELECTROLYTES;
SOLVENTS;
ASSOCIATION;
MIXTURES;
BIOCATALYSIS;
CONDUCTANCE;
SOLVATION;
D O I:
10.1021/acs.jced.6b00343
中图分类号:
O414.1 [热力学];
学科分类号:
摘要:
Conductivities for ionic liquids (ILs) 1-alkyl-3-methylimidazobum chloride ([C(n)mim]Cl, n = 4, 6, 8, 10) + sucrose + water solutions and [C(4)mim]Cl + maltose + water solutions were measured at 298.15 K. Meanwhile, densities, viscosities, and relative permittivities for water + disaccharide mixtures were also measured. The Lee-Wheaton conductivity equation was used to acquire the limiting molar conductivities (Lambda(0)). The Walden products (Lambda(0)eta(0)) were also calculated. The interaction of ILs with disaccharide was discussed in terms of the structure of disaccharides and ILs. Furthermore, values of Lambda(0) for inorganic salts (ordinary electrolyte, such as NaCl/KCl) and Ms (special electrolyte) were compared, indicating that they have approximate limiting molar conductivities, namely, they have not too much difference in electrical conductivity.
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页码:3779 / 3787
页数:9
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