Stepped water isotherm and breakthrough curves on aluminium fumarate metal-organic framework: experimental and modelling study

被引：17
作者：
Bozbiyik, Belgin [1 ]
Van Assche, Tom [1 ]
Lannoeye, Jeroen [2 ]
De Vos, Dirk E. [2 ]
Baron, Gino V. [1 ]
Denayer, Joeri F. M. [1 ]
机构：
[1] Vrije Univ Brussel, Dept Chem Engn, Pl Laan 2, B-1050 Brussels, Belgium
[2] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, Kasteelpk Arenberg 23, B-3001 Leuven, Belgium
来源：
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY | 2017年 / 23卷 / 01期
关键词：
Water adsorption; MOF; Al-fumarate; Breakthrough experiments; HEAT TRANSFORMATION; LOW-PRESSURE; ADSORPTION; STABILITY; SEPARATION; CHROMATOGRAPHY; ADSORBENT; VAPOR; MOFS;
D O I：
10.1007/s10450-016-9847-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Adsorption of water vapour on the Al-fumarate metal-organic framework (MOF) was studied in static and dynamic conditions, by performing gravimetric and fixed bed experiments. A two-step, type IV water isotherm is obtained, which reveals the complexity and the duality of the hydrophilic/hydrophobic behaviour of this MOF. Breakthrough experiments with feed conditions corresponding to three different zones in the water adsorption isotherm were performed to study the effect of isotherm shape on the column dynamics. At low partial pressure of water in the feed, a single breakthrough step is observed while a stepped profile is observed at higher partial pressure of water. These breakthrough curves could be described qualitatively with a simple model accounting for the isotherm shape.
引用
收藏
页码：185 / 192
页数：8
相关论文
共 42 条
[1]   The Structure of the Aluminum Fumarate Metal-Organic Framework A520 [J].
Alvarez, Elsa ;
Guillou, Nathalie ;
Martineau, Charlotte ;
Bueken, Bart ;
Van de Voorde, Ben ;
Le Guillouzer, Clement ;
Fabry, Paul ;
Nouar, Farid ;
Taulelle, Francis ;
de Vos, Dirk ;
Chang, Jong-San ;
Cho, Kyoung Ho ;
Ramsahye, Naseem ;
Devic, Thomas ;
Daturi, Marco ;
Maurin, Guillaume ;
Serre, Christian .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (12) :3664-3668
[2]   Zr- and Hf-Based Metal-Organic Frameworks: Tracking Down the Polymorphism [J].
Bon, Volodymyr ;
Senkovska, Irena ;
Baburin, Igor A. ;
Kaskel, Stefan .
CRYSTAL GROWTH & DESIGN, 2013, 13 (03) :1231-1237
[3]   A microporous metal-organic framework with high stability for GC separation of alcohols from water [J].
Borjigin, Tsolmon ;
Sun, Fuxing ;
Zhang, Jinlei ;
Cai, Kun ;
Ren, Hao ;
Zhu, Guangshan .
CHEMICAL COMMUNICATIONS, 2012, 48 (61) :7613-7615
[4]   Shape selective properties of the Al-fumarate metal-organic framework in the adsorption and separation of n-alkanes, iso-alkanes, cyclo-alkanes and aromatic hydrocarbons [J].
Bozbiyik, Belgin ;
Lannoeye, Jeroen ;
De Vos, Dirk E. ;
Baron, Gino V. ;
Denayer, Joeri F. M. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (04) :3294-3301
[5]   Adsorption and separation of n-hexane and cyclohexane on the UiO-66 metal-organic framework [J].
Bozbiyik, Belgin ;
Duerinck, Tim ;
Lannoeye, Jeroen ;
De Vos, Dirk E. ;
Baron, Gino V. ;
Denayer, Joeri F. M. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2014, 183 :143-149
[6]   Water Stability and Adsorption in Metal-Organic Frameworks [J].
Burtch, Nicholas C. ;
Jasuja, Himanshu ;
Walton, Krista S. .
CHEMICAL REVIEWS, 2014, 114 (20) :10575-10612
[7]   Water adsorption in MOFs: fundamentals and applications [J].
Canivet, Jerome ;
Fateeva, Alexandra ;
Guo, Youmin ;
Coasne, Benoit ;
Farrusseng, David .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5594-5617
[8]   Structure-property relationships of water adsorption in metal-organic frameworks [J].
Canivet, Jerome ;
Bonnefoy, Jonathan ;
Daniel, Cecile ;
Legrand, Alexandre ;
Coasne, Benoit ;
Farrusseng, David .
NEW JOURNAL OF CHEMISTRY, 2014, 38 (07) :3102-3111
[9]   Stability of an Al-Fumarate MOF and Its Potential for CO2 Capture from Wet Stream [J].
Coelho, Juliana A. ;
Ribeiro, Ana Mafalda ;
Ferreira, Alexandre F. P. ;
Lucena, Sebastiao M. P. ;
Rodrigues, Alirio E. ;
de Azevedo, Diana C. S. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2016, 55 (07) :2134-2143
[10]   Stability and degradation mechanisms of metal-organic frameworks containing the Zr6O4(OH)4 secondary building unit [J].
DeCoste, Jared B. ;
Peterson, Gregory W. ;
Jasuja, Himanshu ;
Glover, T. Grant ;
Huang, You-gui ;
Walton, Krista S. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5642-5650
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