Recent Advances in Silver-Catalyzed Transformations of Electronically Unbiased Alkenes and Alkynes

被引：47
作者：
Li, Meng [1 ]
Wu, Wanqing [1 ,2 ]
Jiang, Huanfeng [2 ]
机构：
[1] South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Peoples R China
[2] South China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Peoples R China
来源：
CHEMCATCHEM | 2020年 / 12卷 / 20期
基金：
中国国家自然科学基金;
关键词：
Silver-catalyzed; Electron-unbiased alkenes and alkynes; Functionalization reaction; Cross-coupling reaction; Cyclization reaction; C-H FUNCTIONALIZATION; TERMINAL ALKYNES; INTRAMOLECULAR HYDROAMINATION; STEREOSELECTIVE-SYNTHESIS; REGIOSELECTIVE SYNTHESIS; SULFONYL HYDRAZIDES; UNACTIVATED ALKENES; HIGHLY EFFICIENT; VINYL SULFONES; COINAGE METALS;
D O I：
10.1002/cctc.202000743
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Silver, as one of the most ancient coinage metals, has attracted a plethora of attention from chemists in recent years due to the easy availability, high catalytic efficiency and multiple functions displayed in various chemical processes. In particular, the research in this field has gained a great progress since 2007 and several elegant reviews have been documented in the literature. However, there has been no systematic review concentrating on the transformations of electronically unbiased alkenes and alkynes under silver catalysis till now, though a rapid development in this area is witnessed. Therefore, this review mainly focuses on the recent advances in silver-catalyzed reactions of different electron-unbiased alkenes and alkynes, covering examples of hydrofunctionalization reactions, difunctionalization reactions, cross-coupling reactions as well as cyclization reactions since 2015 to February 2020. In addition, some interesting mechanisms were also discussed.
引用
收藏
页码：5034 / 5050
页数：17
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