Continuous, High-Speed, and Efficient Oil/Water Separation using Meshes with Antagonistic Wetting Properties

被引:109
作者
Dunderdale, Gary J. [1 ]
Urata, Chihiro [1 ]
Sato, Tomoya [1 ]
England, Matt W. [1 ]
Hozumi, Atsushi [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Moriyama Ku, Nagoya, Aichi 4638560, Japan
关键词
polymer brush; superhydrophobicity; superoleophobicity; oil/water separation; ARGET ATRP; POLYMER BRUSH SURFACES; OIL-WATER SEPARATION; COATED MESH; SUPERHYDROPHOBICITY; SUPERHYDROPHILICITY; SUPEROLEOPHOBICITY; WETTABILITY; EQUIPMENT; MEMBRANES; MOTION;
D O I
10.1021/acsami.5b06207
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We report a novel oil/water separation device, allowing continuous, high-speed, and highly efficient purification of large volumes of oily water. This device uses a pair of hydrophilic/hydrophobic polymer-brush-functionalized stainless steel meshes, which have antagonistic wetting properties, i.e., superoleophobic and superhydrophobic properties, when submerged in the opposite liquid phase. This device can purify large volumes of n-hexadecane/water mixture (similar to 1000 L) in a continuous process rather than in batches, to high purities (similar to 99.9% mol/mol) at high flow rates (similar to 5 mL s(-1) cm(-2)), unlike the oil/water separation meshes reported so far.
引用
收藏
页码:18915 / 18919
页数:5
相关论文
共 28 条
[1]   Ultrafast Oleophobic-Hydrophilic Switching Surfaces for Antifogging, Self-Cleaning, and Oil Water Separation [J].
Brown, P. S. ;
Atkinson, O. D. L. A. ;
Badyal, J. P. S. .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (10) :7504-7511
[2]   Mechanically durable, superoleophobic coatings prepared by layer-by-layer technique for anti-smudge and oil-water separation [J].
Brown, Philip S. ;
Bhushan, Bharat .
SCIENTIFIC REPORTS, 2015, 5
[3]   Hydrophobic Modification on Surface of Chitin Sponges for Highly Effective Separation of Oil [J].
Duan, Bo ;
Gao, Huimin ;
He, Meng ;
Zhang, Lina .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (22) :19933-19942
[4]   pH-Dependent Control of Particle Motion through Surface Interactions with Patterned Polymer Brush Surfaces [J].
Dunderdale, Gary ;
Howse, Jonathan ;
Fairclough, Patrick .
LANGMUIR, 2012, 28 (36) :12955-12961
[5]   Polymer Brush Surfaces Showing Superhydrophobicity and Air-Bubble Repellency in a Variety of Organic Liquids [J].
Dunderdale, Gary J. ;
England, Matt W. ;
Urata, Chihiro ;
Hozumi, Atsushi .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (22) :12220-12229
[6]   An Underwater Superoleophobic Surface That Can Be Activated/Deactivated via External Triggers [J].
Dunderdale, Gary J. ;
Urata, Chihiro ;
Hozumi, Atsushi .
LANGMUIR, 2014, 30 (44) :13438-13446
[7]   Large-Scale and Environmentally Friendly Synthesis of pH-Responsive Oil-Repellent Polymer Brush Surfaces under Ambient Conditions [J].
Dunderdale, Gary J. ;
Urata, Chihiro ;
Miranda, Daniel F. ;
Hozumi, Atsushi .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (15) :11864-11868
[8]   Controlling the Motion and Placement of Micrometer-Sized Metal Particles Using Patterned Polymer Brush Surfaces [J].
Dunderdale, Gary J. ;
Howse, Jonathan R. ;
Fairclough, J. Patrick A. .
LANGMUIR, 2011, 27 (19) :11801-11805
[9]   Construction of superhydrophobic and superoleophilic nickel foam for separation of water and oil mixture [J].
Gao, Rui ;
Liu, Qi ;
Wang, Jun ;
Liu, Jingyuan ;
Yang, Wanlu ;
Gao, Zan ;
Liu, Lianhe .
APPLIED SURFACE SCIENCE, 2014, 289 :417-424
[10]   Heavy equipment maintenance wastes and environmental management in the mining industry [J].
Guerin, TF .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2002, 66 (02) :185-199