High-Nuclearity Silver Ethynide Clusters Assembled with Phosphonate and Metavanadate Precursors

被引：102
作者：
Xie, Yun-Peng [1 ,2 ]
Mak, Thomas C. W. [1 ,2 ]
机构：
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
[2] Chinese Univ Hong Kong, Ctr Novel Funct Mol, Shatin, Hong Kong, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 35期
关键词：
clusters; ethynide; oxovanadates; phosphonates; silver; CHLORIDE ANIONS; ALKYNYL CAGE; ORGANIZATION; REACTIVITY; DEVICES; SYSTEM; IONS;
D O I：
10.1002/anie.201202195
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Giant mixed-metal clusters have been assembled with the multinuclear silver(I) tert-butylethynide supramolecular synthon and phosphonate- functionalized oxovanadate building blocks as surface components. Various anionic species can be used as their encapsulated templates. (Picture: Ag 36 cluster anion encapsulating a chloride (sphere) and two [(O 2)(V 2O 6)] 4- template anions (dark green); Ag blue, O red, P yellow, V green). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：8783 / 8786
页数：4
相关论文
共 49 条
[1]  
Bian S.-D., 2009, ANGEW CHEM, V121, P5467
[2]   Snowman-like silver alkynyl cluster consolidated by templating chloride and peripheral trifluoroacetates [J].
Bian, Shu-Dan ;
Wang, Quan-Ming .
CHEMICAL COMMUNICATIONS, 2008, (43) :5586-5588
[3]   A Facile Template Approach to High-Nuclearity Silver(I) Alkynyl Clusters [J].
Bian, Shu-Dan ;
Wu, Hua-Bin ;
Wang, Quan-Ming .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (29) :5363-5365
[4]   High-Nuclearity Silver Clusters Templated by Carbonates Generated from Atmospheric Carbon Dioxide Fixation [J].
Bian, Shu-Dan ;
Jia, Jian-Hua ;
Wang, Quan-Ming .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (10) :3422-+
[5]   Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles [J].
Chakrabarty, Rajesh ;
Mukherjee, Partha Sarathi ;
Stang, Peter J. .
CHEMICAL REVIEWS, 2011, 111 (11) :6810-6918
[6]   A basket tetradecavanadate cluster with blue luminescence [J].
Chen, L ;
Jiang, FL ;
Lin, ZZ ;
Zhou, YF ;
Yue, CY ;
Hong, MC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (24) :8588-8589
[7]   Hybrid Organic-Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications [J].
Dolbecq, Anne ;
Dumas, Eddy ;
Mayer, Cedric R. ;
Mialane, Pierre .
CHEMICAL REVIEWS, 2010, 110 (10) :6009-6048
[8]   Acid-Induced Surface Functionalization of Polyoxometalate by Enclosure in a Polyhedral Silver-Alkynyl Cage [J].
Gao, Guang-Gang ;
Cheng, Ping-Shing ;
Mak, Thomas C. W. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (51) :18257-+
[9]  
Gruber F., 2010, Angew. Chem. Int. Ed, V122, P5044
[10]   {[Ag42(CO3)(C≡ CtBu)27(CH3CN)2][CoW12O40]2}[BF4]: An Intercluster Sandwich Compound [J].
Gruber, Franziska ;
Jansen, Martin .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (29) :4924-4926
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