Molecular Engineering of Organic Sensitizers with Planar Bridging Units for Efficient Dye-Sensitized Solar Cells

被引:26
|
作者
Lim, Kimin [1 ]
Ju, Myung Jong [2 ,3 ]
Na, Jongbeom [4 ]
Choi, Hyeju [1 ]
Song, Min Young [1 ]
Kim, Byeonggwan [4 ]
Song, Kihyung [5 ]
Yu, Jong-Sung [1 ]
Kim, Eunkyoung [4 ]
Ko, Jaejung [1 ]
机构
[1] Korea Univ, Dept Chem Mat, Sejong 339700, South Korea
[2] Korea Univ, Global GET Future Lab, Sejong 339700, South Korea
[3] Korea Univ, Dept Adv Mat Chem, Sejong 339700, South Korea
[4] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea
[5] Korea Natl Univ Educ, Dept Chem, Cheongwon 363791, Chungbuk, South Korea
基金
新加坡国家研究基金会;
关键词
cobalt; electrolytes; impedance; sensitizers; CONVERSION-EFFICIENCY; HIGHLY EFFICIENT; PERFORMANCE; ELECTROLYTE; ABSORPTIVITY; LIQUID;
D O I
10.1002/chem.201300736
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Here comes the sun: Three highly efficient organic sensitizers with sterically hindered fluorenyl units and planar indenothiophene derivatives were designed and synthesized (see figure). Devices based on one of these compounds, JK-303, gave overall conversion efficiencies of 8.69, 9.04, 7.27, and 5.82 % using I-/I3-, CoII/CoIII, polymer gel, and solid-state electrolytes, respectively. These efficiencies are some of the highest reported for DSSCs based on organic sensitizers. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:9442 / 9446
页数:5
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