Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH)SnCl3(H2O)] • 3H2O

被引：0
|
作者：
Martsinko, E. E. [1 ]
Ilyukhin, A. B. [2 ]
Seifullina, I. I. [1 ]
Chebanenko, E. A. [1 ]
Sergienko, V. S. [2 ]
机构：
[1] Mechnikov Univ, UA-270100 Odessa, Ukraine
[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 39卷 / 07期
关键词：
PROTEASE INHIBITION; MOLECULAR-STRUCTURE; REACTIVITY;
D O I：
10.1134/S1070328413070075
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The binuclear tin(IV) complex with N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid (H(4)Hedtra) is synthesized. The compound is characterized by elemental analysis, thermogravimetry, and IR spectroscopy. An X-ray diffraction analysis of complex Sn(mu-Hedtra)(mu-OH)SnCl3(H2O)] center dot 3H(2)O (I) is carried out. Structure I is formed by the binuclear complexes and molecules of water of crystallization. One of the tin atoms coordinates six "active" sites Hedtra(4-) (the alcohol branch is deprotonated and forms a bridge between two tin atoms) and the bridging hydroxo group. The polyhedron is a pentagonal bipyramid. The octahedral environment of the second tin atom is formed by two bridging oxygen atoms, three chlorine atoms (fac isomer), and a coordination water molecule.
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页码：505 / 509
页数：5
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