Sequence-Dependent Assembly to Control Molecular Interface Properties

被引：23

作者：

de Ruiter, Graham ^{[1
]}

Lahav, Michal ^{[1
]}

Keisar, Hodaya ^{[1
]}

van der Boom, Milko E. ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 02期

基金：

以色列科学基金会;

关键词：

electrochemistry; interfaces; metal complexes; molecular materials; sequence-dependent assembly; METAL-ORGANIC FRAMEWORKS; ELECTRON-TRANSFER; FILMS; WIRES; COMPLEXES; POLYMERS; RECTIFICATION; MULTILAYER; RUTHENIUM; CIRCUITS;

D O I：

10.1002/anie.201207467

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Variation's what you need: Variation of the assembly sequence in which layers of two isostructural metal complexes are built up leads to molecular materials with electrochemical properties that depend on the assembly sequence. These properties vary from reversible electron transfer to unidirectional current flows and even charge trapping. The sequence-dependent assembly strategy has implications for various disciplines that involve self-assembly. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：704 / 709

页数：6

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