IR and NMR time-resolved studies on the hydrolysis and condensation of methacryloxyalkylsilanes

被引：14

作者：

Stangar, Urska Lavrencic ^{[3
]}

Sassi, Alessandro ^{[4
]}

Venzo, Alfonso ^{[1
,2
]}

Zattin, Andrea ^{[1
,2
]}

Japelj, Bostjan ^{[3
]}

Orel, Boris ^{[3
]}

Gross, Silvia ^{[1
,2
]}

机构：

[1] Univ Padua, CNR ISTM, I-35131 Padua, Italy

[2] Univ Padua, Dipartimento Sci Chim, INSTM UdR Padova, I-35131 Padua, Italy

[3] Natl Inst Chem, Lab Spect Mat, Ljubljana 1000, Slovenia

[4] Univ Padua, CNR ISTM, Dipartimento Proc Chim Ingn, I-35131 Padua, Italy

来源：

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY | 2009年 / 49卷 / 03期

关键词：

Methacryloxytrialkoxysilanes; Sol-gel; NMR; IR; Kinetics; Time resolved studies; MAMTES; MAPTMS; ORGANIC-INORGANIC HYBRID; MOLECULAR BUILDING-BLOCKS; OXIDES MO2-SIO2 M; SILICA; OXOCLUSTERS; FUNCTIONALIZATION; NANOPARTICLES; SPECTROSCOPY; EVOLUTION; BEHAVIOR;

D O I：

10.1007/s10971-008-1882-1

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The sol-gel reactions of the two methacrylate-modified silanes methacryloxymethyltriethoxysilane (MAMTES) and methacryloxypropyltrimethoxysilane (MAPTMS) were followed by using two independent time-resolved spectroscopic methods, viz., IR ATR and NMR with the aim to optimise their pre-hydrolysis times and consequently their use as precursors for hybrid materials. Time resolved measurements were carried out on the two systems under sol-gel conditions. Whereas the hydrolysis of both siloxanes is very fast, condensation proceeds gradually and is not completely finished within 5 h.

引用

页码：329 / 335

页数：7

共 50 条

[31] TIME-RESOLVED STUDIES OF EXCITONIC POLARITONS
AAVIKSOO, J
JOURNAL OF LUMINESCENCE, 1991, 48-9 : 57 - 66
[32] TIME-RESOLVED STUDIES OF BIEXCITONS IN GAAS
STEINER, TW
STEELE, AG
CHARBONNEAU, S
THEWALT, MLW
KOTELES, ES
ELMAN, B
SOLID STATE COMMUNICATIONS, 1989, 69 (12) : 1139 - 1142
[33] TIME-RESOLVED FLUORESCENCE STUDIES ON EXCIPLEXES
NAKASHIMA, N
MATAGA, N
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1972, 79 (3-4): : 150 - +
[34] Time-Resolved Diffusion NMR Measurements for Transient Processes
MacDonald, Thomas S. C.
Price, William S.
Beves, Jonathon E.
CHEMPHYSCHEM, 2019, 20 (07) : 926 - 930
[35] Time-resolved IR and XAFS studies in organometallic photochemistry: Alkane and noble gas complexes and solvation
George, Mike
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
[36] Photophysical and Photochemical Properties of 4-Thiouracil: Time-Resolved IR Spectroscopy and DFT Studies
Zou, Xiaoran
Dai, Xiaojuan
Liu, Kunhui
Zhao, Hongmei
Song, Di
Su, Hongmei
JOURNAL OF PHYSICAL CHEMISTRY B, 2014, 118 (22): : 5864 - 5872
[37] Utilizing relativistic time dilation for time-resolved studies
Daoud, Hazem
Miller, R. J. Dwayne
JOURNAL OF CHEMICAL PHYSICS, 2021, 154 (11):
[38] INTERMEDIATES IN ORGANOMETALLIC PHOTOCHEMISTRY - FAST TIME-RESOLVED IR SPECTROSCOPY
TURNER, JJ
HEALY, MA
POLIAKOFF, M
JOURNAL OF INFORMATION RECORDING MATERIALS, 1987, 15 (06): : 375 - 383
[39] Time-resolved FT-IR Spectroscopy of Membrane Proteins
Radu, Ionela
Schleeger, Michael
Nack, Melanie
Heberle, Joachim
AUSTRALIAN JOURNAL OF CHEMISTRY, 2011, 64 (01) : 9 - 15
[40] Time-resolved IR spectroscopy of a trinuclear palladium complex in solution
Zimmer, M.
Rupp, F.
Singer, P.
Walz, F.
Breher, F.
Klopper, W.
Diller, R.
Gerhards, M.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (21) : 14138 - 14144

← 1 2 3 4 5 →