A highly efficient "metalloligand'' strategy for the synthesis of ternary Ln-Ru-W hybrids

被引:26
作者
Wang, Lei [1 ]
Yang, Weiting [1 ]
Yi, Fei-Yan [1 ]
Wang, Hao [1 ]
Xie, Zhigang [1 ]
Tang, Jinkui [1 ]
Sun, Zhong-Ming [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Jilin, Peoples R China
关键词
METAL-ORGANIC FRAMEWORKS; POLYOXOMETALATE; PHOTOCATALYSIS; PORPHYRIN; CLUSTERS; DESIGN; SITES; STATE;
D O I
10.1039/c3cc43277g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of novel ternary Ln-Ru-W hybrids constructed by metalloligands ([Ru-II(bpy)(2)(4,4'-dcbpy)](PF6)(2), m-H2LRu) and high-nuclear lanthanide clusters have been successfully synthesized using an efficient "metalloligand'' strategy for the first time. Slow magnetic relaxation has been observed within the Dy-based hybrid.
引用
收藏
页码:7911 / 7913
页数:3
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