Giant improvement of thermoelectric power factor of Bi2Te3 under pressure

被引:150
作者
Ovsyannikov, Sergey V. [1 ]
Shchennikov, Vladimir V. [1 ]
Vorontsov, Grigoriy V. [1 ]
Manakov, Andrey Y. [2 ]
Likhacheva, Anna Y. [3 ]
Kulbachinski, Vladimir A. [4 ]
机构
[1] Russian Acad Sci, Urals Div, Inst Met Phys, High Pressure Grp, Ekaterinburg 620041, Russia
[2] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
[3] Russian Acad Sci, Inst Mineral & Petrog, Siberian Div, Novosibirsk 630090, Russia
[4] Moscow MV Lomonosov State Univ, Dept Phys, Moscow 119991, Russia
关键词
D O I
10.1063/1.2973201
中图分类号
O59 [应用物理学];
学科分类号
摘要
The pressure (P) dependencies of both the thermopower (Seebeck effect) S and the electrical resistance (R) for p-type single crystals of Bi2Te3 and indium-doped bismuth telluride (InxBi2-xTe3, 0.04 <= x <= 0.10) are reported on a pressure range of 0-8.5 GPa. The thermoelectric power factor (efficiency) (alpha = S-2/R) exhibits two maxima: the first one near similar to 1 GPa and the second near similar to 2.5-4.5 GPa. These features evidence a giant increase in the power factor by a factor of similar to 10. Possible values of the dimensionless figure of merit under pressure are also estimated. The maxima are explained in terms of pressure-driven changes in an electron structure. The second feature may be also addressed to an intermediate high-pressure phase detected in x-ray diffraction studies. (C) 2008 American Institute of Physics.
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页数:5
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