Stannous Chloride as a Versatile Catalyst in Organic Synthesis

被引：0

作者：

Singh, Okram Mukherjee ^{[1
]}

Devi, Laishram Ronibala ^{[1
]}

机构：

[1] Manipur Univ, Dept Chem, Imphal 795003, Manipur, India

来源：

MINI-REVIEWS IN ORGANIC CHEMISTRY | 2013年 / 10卷 / 01期

关键词：

Stannous chloride; catalyst; reduction; allylation; multicomponent reaction; ONE-POT SYNTHESIS; REDUCTIVE COUPLING REACTIONS; CONDENSATION REACTION; EFFICIENT SYNTHESIS; BIGINELLI REACTION; COPPER(II)/TIN(II) REAGENT; MULTICOMPONENT REACTIONS; IMPROVED PROTOCOL; CARBOXYLIC-ACIDS; DIHYDROPYRIMIDINONES;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stannous chloride, an inexpensive mild Lewis acid has been used in various organic synthetic operations. It was used in reducing various functional groups in the earlier days. The recent trends however expanded the scope of its applications in organic synthesis using it as an efficient catalyst. This review highlights the catalytic potential of this reagent in a wide range of reactions such as allylation, propargylation, multicomponent reactions and syntheses of bioactive heterocycles.

引用

页码：84 / 96

页数：13

共 77 条

[1] Stannous Chloride Dihydrate: A Novel and Efficient Catalyst for the Synthesis of gem-Dihydroperoxides from Ketones and Aldehydes [J].

Azarifar, Davood ;

Khosravi, Kaveh ;

Soleimanei, Fatemeh .

SYNTHESIS-STUTTGART, 2009, (15) :2553-2556

[2] One-pot synthesis of 2-(2-hydroxyaryl)quinolines:: reductive coupling reactions of 2′-hydroxy-2-nitrochalcones [J].

Barros, AIRNA ;

Silva, AMS .

TETRAHEDRON LETTERS, 2003, 44 (31) :5893-5896

[3] Stannous chloride-mediated reductive cyclization - Rearrangement of nitroarenyl ketones [J].

Bates, DK ;

Li, KX .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (24) :8662-8665

[4]

Beaz G., 1991, COMPREHENSIVE ORGANI, V6, P323

[5] STANNOUS CHLORIDE MEDIATED FORMATION OF (9-ANTHRYL)METHYL DIMERS FROM (HALOGENOMETHYL)ANTHRACENES - GROUND-STATE AND ADIABATIC EXCITED-STATE REVERSIBILITY OF INTRAMOLECULAR [4 + 2] CYCLO-ADDITIONS [J].

BECKER, HD ;

ANDERSSON, K ;

SANDROS, K .

JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (23) :4549-4555

[6] A simple method for the preparation and selective functionalization of 4,5-diaminopyrazoles [J].

Blass, BE ;

Srivastava, A ;

Coburn, KR ;

Faulkner, AL ;

Seibel, WL .

TETRAHEDRON LETTERS, 2003, 44 (14) :3009-3011

[7] Green chemistry approaches to the synthesis of 5-alkoxycarbonyl-4-aryl-3,4-dihydropyrimidin-2(1H)-ones by a three-component coupling of one-pot condensation reaction:: Comparison of ethanol, water, and solvent-free conditions [J].

Bose, DS ;

Fatima, L ;

Mereyala, HB .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (02) :587-590

[8] Preparation of Novel Polycyclic Heterocycles Using a Tin(II) Chloride Dihydrate-Mediated Deacetalisation-Bicyclisation Sequence [J].

Cayley, Alex N. ;

Gallagher, Katherine A. ;

Menard-Moyon, Cecilia ;

Schmidt, Jan Peter ;

Diorazio, Louis J. ;

Taylor, Richard J. K. .

SYNTHESIS-STUTTGART, 2008, (23) :3846-3856

[9] Intramolecular amination catalysed by ruthenium and palladium. Synthesis of 2-acyl indoles and 2-aryl quinolines by carbonylation of 2-nitrochalcones [J].

Cenini, S ;

Bettettini, E ;

Fedele, M ;

Tollari, S .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 111 (1-2) :37-41

[10] Chemistry of thyroxine: an historical perspective and recent progress on its synthesis [J].

Chemburkar, Sanjay R. ;

Deming, Kris C. ;

Reddy, Rajarathnam E. .

TETRAHEDRON, 2010, 66 (11) :1955-1962

← 1 2 3 4 5 6 7 8 →