The C-2 selective azide opening reaction of trans-2,3-epoxy alcohols by NaN3 and PhB(OH)2

被引：23

作者：

Hayakawa, H ^{[1
]}

Okada, N ^{[1
]}

Miyazawa, M ^{[1
]}

Miyashita, M ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 24期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/S0040-4039(99)00798-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The azide opening reaction of trans-2,3-epoxy alcohols with NaN3 and PhB(OH)(2) in DMF occurred regio- and stereoselectively at the C-2 position giving rise to phenylboronates of trans-2-azido-1,3-diols in high yields. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：4589 / 4592

页数：4

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