Screening test of solid amine sorbents for CO2 capture

被引:103
作者
Lee, Seungmoon [1 ]
Filburn, Thomas P. [1 ]
Gray, Mac [2 ]
Park, Jin-Won [3 ]
Song, Ho-Jun [3 ]
机构
[1] Univ Hartford, Dept Mech Engn, Clean Energy Inst, Hartford, CT 06117 USA
[2] US DOE, Natl Energy Technol Lab, Pittsburgh, PA 15236 USA
[3] Yonsei Univ, Dept Chem Engn, Seoul 120749, South Korea
关键词
D O I
10.1021/ie8006984
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this study, the absorption properties of CO2 in seven different solid amine absorbents were measured. The specific characteristics, such as absorption capacity, absorption/desorption rate, cyclic capacity, cycle decay effect, temperature of reaction in the absorber, and optimal conditions for the CO,) absorption process were measured. This absorption process occurred at two temperatures-either 296.15 or 313.15 K-while the desorption process temperature was raised to 348.15 K. The solid amines (TEPAN and E-100AN) demonstrated higher cyclic capacity than others under these conditions. Our testing showed high reproducibility for the CO2 capture of TEPAN and E-100AN in measuring their cyclic capacity. Diminished cyclic capacities were noted for the MEA and 194B materials, with measured drops at the third cycle of about 16.17% and 15.79% lower than those in the first cycle, respectively.
引用
收藏
页码:7419 / 7423
页数:5
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