Synthesis of [bis(1,3-dithiole-2-thione-4,5-dithiolato)indium(III)]- salts, [Q][In(dmit)2]:: crystal structure of [tetrabutylammonium] [bis(1,3-dithiole-2-thione-4,5-dithiolato)indium(III)]

被引：10
作者：
Avila, BMF
Comerlato, NM
Howie, RA
Wardell, JL
机构：
[1] Univ Aberdeen, Dept Chem, Old Aberdeen AB24 3UE, Scotland
[2] Univ Fed Rio de Janeiro, Inst Quim, Dept Quim Inorgan, BR-21945970 Rio De Janeiro, Brazil
来源：
INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 05期
关键词：
indium; dmit; crystal structure; 1,3-dithiole-2-thione-4.5-dithiolate; 1,2-dithiolate;
D O I：
10.1016/j.ica.2003.11.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ionic complexes, [Q][In-III (dmit)(2)] (7), have been obtained from reactions of InCl3, Na-2(dmit) and [Q]Br [Q = NEt4 and NBu4: H-2(dmit) = 4,5-dimercapto-1,3-dithiole-2-thione]. As established by X-ray crystallography, using synchrotron radiation at 120 K, (7: Q = NBu4) is an ionic compound, with the cations well separated from the anions. The anions are in the form of chains of edge sharing octahedra in which distinct six coordinate In atoms are linked by bridging thiolato-S leading to the formation of In2S2 rings. For each dmit ligand, one thiolato S atom acts as a monodentate centre and the other as a p-bridge. The In-S bond lengths fall into three groupings: 2.5301(17)-2.5400(17) [monodentate S], 2.5905(17)-2.6171(17) and 2.7236(17)-2.7589(17) Angstrom [the latter two. bridging S]. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：1487 / 1493
页数：7
相关论文
共 50 条
  • [41] 1-(2,4-Dichlorobenzyl)pyridinium bis(2-sulfanylidene-1,3-dithiole-4,5-dithiolato-κ2S,S′)nickelate(III)
    Liu, Guang-Xiang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1654 - U1533
  • [42] A new low bandgap hybrid polymer film obtained by electropolymerization of 3,4-ethylenedioxythiophene with bis(1,3-dithiole-2-thione-4,5-dithiolate)platinate(II) dianion, PEDOT/[Pt(dmit)2]2-
    Bernardo da Cruz, Antonio Gerson
    Leyva, Maria Elena
    Simao, Renata Antoun
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2018, 22 (05) : 1459 - 1469
  • [43] Peculiarities of crystal structures and magnetic properties of Cu(II) and Ni(II) mixed-ligand complexes on the 1,3-dithiole-2-thione-4,5-dithiolate basis
    Starodub, V. A.
    Vitushkina, S. V.
    Kamenskyi, D.
    Anders, A. G.
    Cheranovskii, V. O.
    Schmidt, H.
    Steinborn, D.
    Potocnak, I.
    Kajnakova, M.
    Radvakova, A.
    Feher, A.
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2012, 73 (02) : 350 - 356
  • [44] Synthesis, crystal structure and third-order nonlinear optical behavior of a novel dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate
    Liu, CM
    Zhang, DQ
    Song, YL
    Zhan, CL
    Li, YL
    Zhu, DB
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2002, (07) : 1591 - 1594
  • [45] Third-order optical nonlinearities of an organometallic complex Bis(tetra-n-propylammonium)bis(2-thioxo-1,3-dithiole-4,5-dithiolato)cuprate(II) doped in solid PMMA films
    Zhang, J. N.
    Wang, X. Q.
    Ren, Q.
    Yang, H. L.
    Chen, J. W.
    Sun, Q.
    Li, G. C.
    Li, T. B.
    OPTICS AND LASER TECHNOLOGY, 2011, 43 (03) : 679 - 682
  • [46] Experimental and theoretical investigation of the magnetic and photoconductive nature of a novel two-dimensional, mixed-valence bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate molecular solid
    Yang, Hao
    Liu, Jian-Lan
    Zhou, Lan-Cheng
    Ren, Xiao-Ming
    INORGANIC CHEMISTRY FRONTIERS, 2014, 1 (05): : 426 - 433
  • [47] Crystal structures, magnetic and electrical properties of two new two-dimensional bis(2-thioxo-1, 3-dithiole-4, 5-dithiolato)nickelate salts
    Sun, Xin
    Yang, Hao
    Xu, Hai-Yan
    Liu, Jian-Lan
    Zhou, Lan-Cheng
    Ren, Xiao-Ming
    SYNTHETIC METALS, 2015, 209 : 112 - 118
  • [48] COORDINATION CHEMISTRY OF 1,3-DITHIOLE-2-SELONE-4,5-DISELENOLATE (DSISE) AND 1,3-DITHIOLE-2-SELONE-4,5-DITHIOLATE (DMISE) - CRYSTAL AND MOLECULAR-STRUCTURE OF TETRABUTYLAMMONIUM BIS(1,3-DITHIOLE-2-SELONE-4,5-DISELENOLATO)NICKELATE(II) AND BIS(1,3-DITHIOLE-2-SELONE-4,5-DISELENOLATO)NICKELATE(III), [(N-C4H9)4N]2[NI(DSISE)2 AND (N-C4H9)4[NI(DSISE)2]
    OLK, RM
    OLK, B
    ROHLOFF, J
    REINHOLD, J
    SIELER, J
    TRUBENBACH, K
    KIRMSE, R
    HOYER, E
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 609 (03): : 103 - 116
  • [49] 4,5-Bis[(triorganotin)thiolato]-1,3-dithiole-2-thione, (R3Sn)2(dmit), 4,5-bis [(triorganotin)thiolato]-1,3-dithiole-2-one, (R3Sn)2(dmio), compounds:: Crystal structures of (cyclohexyl3Sn)2(dmio), (Ph3Sn)2(dmit) and (Ph3Sn)2(dmio)
    Bordinhao, J
    Comerlato, NM
    Ferreira, GB
    Howie, RA
    da Silva, CXA
    Wardell, JL
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (08) : 1598 - 1605
  • [50] Preparation, spectrographic characterization, thermal, second and third order nonlinear optical properties of 4,5-bis(foroylsulfanyl)-1,3-dithiole-2-thione
    Wang, X. Q.
    Fang, H. L.
    Ren, Q.
    Sun, J.
    Li, T. B.
    Zhang, G. H.
    Xu, D.
    LASER PHYSICS, 2009, 19 (08) : 1858 - 1866
12345